Burggraaf / Cot Fundamentals of Inorganic Membrane Science and Technology

1. Auflage 1996
ISBN: 978-0-08-053470-1
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 689 Seiten, Web PDF

Inorganic membrane science and technology is a new field of membrane separation technology which until recently was dominated by the earlier field of polymer membranes. Currently the subject is undergoing rapid development and innovation.The present book describes the fundamental principles of both synthesis of inorganic membranes and membrane supports and also the associated phenomena of transport and separation in a semi-quantitative form.Features of this book:- Examples are given which illustrate the state-of-the-art in the synthesis of membranes with controlled properties- Future possibilities and limitations are discussed- The reader is provided with references to more extended treatments in the literature- Potential areas for future innovation are indicated.By combining aspects of both the science and technology of inorganic membranes this book serves as a useful source of information for scientists and engineers working in this field. It also provides some observations of important investigators who have contributed to the development of this subject.

Autoren/Hrsg.

Burggraaf, A. J.

Cot, L.

Inhaltsverzeichnis

1;Cover;1
2;Contents;8
3;Preface;6
4;List of contributors;18
5;CHAPTER 1. GENERAL OVERVIEW, TRENDS AND PROSPECTS;20
5.1;1.1 Introduction;20
5.2;1.2 Market Situation and Prospects;21
5.3;1.3 Main Barriers to Technological Development and Acceptance;22
5.4;1.4 Trends, Technological and Scientific Prospects;28
5.5;References;38
6;CHAPTER 2. IMPORTANT CHARACTERISTICS OF INORGANIC MEMBRANES;40
6.1;2.1 Introduction;40
6.2;2.2 Types of Inorganic Membranes;40
6.3;2.3 Microstructural Pore and Pore Network Characteristics;42
6.4;2.4 Architecture of Membrane Systems;46
6.5;2.5 Some General Characteristics;50
6.6;2.6 Considerations on Chemical Resistance;52
6.7;References;53
7;CHAPTER 3. ADSORPTION PHENOMENA IN MEMBRANE SYSTEMS;54
7.1;3.1 Introduction;54
7.2;3.2 Adsorption Isotherms;55
7.3;3.3 Experimental Techniques ;62
7.4;3.4 Adsorption on Membranes ;76
7.5;3.5 Summary ;83
7.6;References;83
8;CHAPTER 4. METHODS FOR THE CHARACTERISATION OF POROUS STRUCTURE IN MEMBRANE MATERIALS;86
8.1;4.1 General Introduction;86
8.2;4.2 Description of Porous Materials „ Definitions;88
8.3;4.3 Static Characterisation Techniques;93
8.4;4.4 Dynamic Characterisation Techniques;117
8.5;4.5 Conclusion and Recommendations;125
8.6;References;129
9;CHAPTER 5. CERAMIC PROCESSING TECHNIQUES OF SUPPORT SYSTEMS FOR MEMBRANES SYNTHESIS;138
9.1;5.1 Introduction;138
9.2;5.2 Extrusion;140
9.3;5.3 Tape Casting;149
9.4;5.4 Specific Characterization Methods for Supports;153
9.5;5.5 Conclusion;156
9.6;References;157
10;CHAPTER 6. PREPARATION OF ASYMMETRIC CERAMIC MEMBRANE SUPPORTS BY DIP-COATING;160
10.1;6.1 Introduction;160
10.2;6.2 Supports for Ceramic Membranes;162
10.3;6.3 Dip-coating with Porous Substrates;202
10.4;6.4 Applications;228
10.5;6.5 Final Remarks;237
10.6;Acknowledgements;237
10.7;List of Symbols;238
10.8;References;240
11;CHAPTER 7. SOL-GEL CHEMISTRY AND ITS APPLICATION TO POROUS MEMBRANE PROCESSING;246
11.1;7.1 Introduction;246
11.2;7.2 Pore Formation in Sol-Gel Derived Ceramic Membranes;248
11.3;7.3 Colloidal Suspensions to Prepare Mesoporous Membranes;251
11.4;7.4 Inorganic Polymers to Prepare Microporous Membranes;256
11.5;7.5 The Concept of Nanophase Ceramics Applied to the Preparation of Microporous Membranes;259
11.6;7.6 Tailor-made Porous Membranes via Templates Containing Systems;264
11.7;7.7 Conclusion;273
11.8;References;274
12;CHAPTER 8. FUNDAMENTALS OF MEMBRANE TOP-LAYER SYNTHESIS AND PROCESSING;278
12.1;8.1 Synthesis and Processing of Supported Mesoporous Membranes;278
12.2;8.2 Synthesis and Processing of Supported Microporous Membranes;317
12.3;8.3 Conclusions and Evaluation;341
12.4;References;343
13;CHAPTER 9. TRANSPORT AND SEPARATION PROPERTIES OF MEMBRANES WITH GASES AND VAPOURS;350
13.1;9.1 Introduction;350
13.2;9.2 Gas Transport in Simple Membrane Structures;352
13.3;9.3 Separation of Binary Mixtures in Simple Mesoporous Membranes;383
13.4;9.4 Permeation and Separation in Microporous Membranes;393
13.5;9.5 Permeation and Separation in More Complicated Systems;432
13.6;9.6 Overview of Important Results;435
13.7;9.7 Conclusions and Evaluation;443
13.8;List of Symbols;444
13.9;References;446
14;CHAPTER 10. DENSE CERAMIC MEMBRANES FOR OXYGEN SEPARATION;454
14.1;10.1 Introduction;454
14.2;10.2 General Survey;455
14.3;10.3 Fundamentals;468
14.4;10.4 Solid Oxide Electrolytes;481
14.5;10.5 Introducing Electronic Conduction in Fluorite-type Oxygen Ion Conductors;491
14.6;10.6 Accceptor-doped Perovskite and Perovskite-related Oxides;498
14.7;10.7 Final Remarks;529
14.8;Acknowledgements;532
14.9;List of Abbreviations and Symbols;532
14.10;References;534
15;CHAPTER 11 . CURRENT DEVELOPMENTS AND FUTURE RESEARCH IN CATALYTIC MEMBRANE REACTORS;548
15.1;11.1 Introduction;548
15.2;11.2 Dense Metal Membrane Reactors;551
15.3;11.3 Porous Inorganic Membrane Reactors;556
15.4;11.4 Solid Oxide Membranes;565
15.5;11.5 Theoretical Considerations;568
15.6;11.6 Emerging Applications;574
15.7;11.7 Concluding Remarks;579
15.8;Acknowledgements;580
15.9;References;580
16;CHAPTER 12. TRANSPORT AND FOULING PHENOMENA IN LIQUID PHASE SEPARATION WITH INORGANIC AND HYBRID MEMBRANES;588
16.1;12.1 Introduction;588
16.2;12.2 Basic Phenomena in Pressure Driven Processes;589
16.3;12.3 Recent Developments in Microfiltration and Ultrafiltration with Ceramic Membranes;609
16.4;12.4 Nanofiltration with Ceramic Membranes;614
16.5;12.5 Prospective Aspects;625
16.6;12.6 Conclusion;632
16.7;References;633
17;CHAPTER 13. APPLICATIONS OF CERAMIC MEMBRANES IN LIQUID FILTRATION;638
17.1;13.1 Introduction;638
17.2;13.2 Treatment of Wastes;639
17.3;13.3 Regeneration;642
17.4;13.4 Processing;646
17.5;Acknowledgements;633
17.6;References;633
18;CHAPTER 14. FEASIBILITY OF THE APPLICATION OF POROUS INORGANIC GAS SEPARATION MEMBRANES IN SOME LARGE-SCALE CHEMICAL PROCESSES;660
18.1;14.1 Introduction;660
18.2;14.2 Background Information;662
18.3;14.3 Gas Separation Applications for Inorganic Membranes;667
18.4;14.4 Conclusions;692
18.5;Acknowledgements;693
18.6;List of Symbols and Abbreviations;694
18.7;Appendix;695
18.8;References;695
19;Subject Index;700