Conjugated Polymer Synthesis and Materials Applications

1. Auflage 2026
ISBN: 978-3-527-35443-6
Verlag: Wiley-VCH GmbH

Buch, Englisch, 416 Seiten, Format (B × H): 170 mm x 244 mm

This is the second volume edited by leading expert Prof. Yoshiki Chujo on the evolving topic of conjugated polymer synthesis. Since publication of the first volume in 2010, new methodologies have been developed and the materials from such conjugated polymers are now crucially important in varied electrical, optical, and magnetic applications. This new volume summarizes major developments in the synthesis of new conjugated polymers, novel methodologies for the preparation of conjugated polymers, and inorganic-elements containing mainchain-type conjugated polymers. Topics covered include:
- Living conjugated polymers
- Cyclophane conjugated polymers
- P- and As-containing conjugated polymers
- Low bandgap conjugated polymers
- 3-D and helical conjugated polymers
- Conjugated polymers for organic solar cells and organic electronic devices
 
Keywords: Conjugated polymers, transition metal catalysis, living polymerization, polycondensation, optical materials, electrical
materials, magnetic materials, biomedical materials

Autoren/Hrsg.

Chujo, Yoshiki

Fachgebiete

• Naturwissenschaften Chemie Organische Chemie
• Technische Wissenschaften Maschinenbau | Werkstoffkunde Technische Mechanik | Werkstoffkunde Materialwissenschaft: Elektronik, Optik
• Technische Wissenschaften Verfahrenstechnik | Chemieingenieurwesen | Biotechnologie Technologie der Kunststoffe und Polymere

Inhaltsverzeichnis

Preface
 
1 TRANSITION-METAL-CATALYZED POLYCONDENSATION
1.1 Introduction
1.2 Ni-Catalyzed Polycondensation
1.3 Pd-Catalyzed Polycondensation
1.4 Pd-Catalyzed Polycondensation via C-H Bond Functionalization
1.5 Cu- and Fe-Catalyzed Polycondensation
1.6 Other Transition-Metal-Catalyzed Polymerizations
1.7 Summary
 
2 LIVING CONJUGATED POLYMERS
2.1 Introduction
2.2 Metal Pi-Binding in CTP
2.3 Common Catalysts in CTP
2.4 Kumada-Corriu Catalyst-Transfer Polycondensation (KCTP)
2.5 Murahashi Catalyst-Transfer Polycondensation (MCTP)
2.6 Negishi Catalyst-Transfer Polycondensation (NCTP)
2.7 Suzuki-Miyaura Catalyst-Transfer Polycondensation (SMCTP)
2.8 Stille CTP
2.9 Buchward-Hartwig Amination and Direct Arylation Polymerization (C-H Activation)
2.10 Chain-Growth Polymerization of Aromatic without Metals
2.11 Conclusions
 
3 OPTICALLY ACTIVE THROUGH-SPACE CONJUGATED POLYMERS BASED ON PLANAR CHIRAL [2.2]PARACYCLOPHANE
3.1 Introduction
3.2 Through-Space Conjugation of [2.2]Paracyclophane-Based Conjugated Polymers
3.3 Optically Active Through-Space Conjugated Polymers Based on Planar Chiral [2.2]Paracyclophane
3.4 Optically Active Through-Space Conjugated Cyclic Oligomers Based on Planar Chiral [2.2]Paracyclophane
3.5 Conclusion
 
4 DEVELOPMENT OF SOLID-STATE LUMINESCENT CONJUGATED POLYMERS CONTAINING BORON ELEMENT-BLOCKS AND THEIR APPLICATIONS
4.1 Introduction
4.2 Boron Ketoiminates
4.3 Rational Design for AIE-Active Molecules Based on Excitation-Driven Complexes
4.4 AIE-Active Materials Having NIR Luminescent Properties
4.5 Conclusion
 
5 ARSENIC-CONTAINING CONJUGATED POLYMERS
5.1 Introduction
5.2 Arsenic in Organic Compounds
5.3 As-C Bond Formation
5.4 Arsenic-Containing ¿-Conjugated Systems
5.5 Poly(vinylene-arsine)s
5.6 Arsole Polymers
5.7 Pi-Conjugated Polymers with Other Arsenic Units
5.8 Conclusions
 
6 CARBORANE-CONTAINING CONJUGATED POLYMERS AND THEIR APPLICATIONS FOR OPTOELECTRONIC MATERIALS
6.1 Introduction
6.2 Advanced Functional Materials
6.3 Electronic Properties of Carborane-Containing Conjugated Polymers
6.4 Luminescent Materials
6.5 Photochemistry of o-Carboranes
6.6 Applications for Solid-State Luminescent Materials
6.7 Stimuli-Responsive Luminochromic Materials
6.8 Conclusion
 
7 LOW BANDGAP CONJUGATED POLYMERS
7.1 Introduction
7.2 Design Principles of LBG-CPs
7.3 Synthesis of LBG-CPs
7.4 Application of LBG-CPs
7.5 Conclusion and Perspective
 
8 POLYMERS WITH THREE-DIMENSIONAL CONJUGATED MOLECULES
8.1 Introduction
8.2 Corannulene Containing Polymer
8.3 Supramolecular Polymers Based on Bowl-Shaped Pi-Conjugated molecules
8.4 Helicene-Based Polymers
8.5 Conclusion and Outlook
 
9 CONJUGATED POLYMERS FOR ENERGY STORAGE DEVICES
9.1 Introduction
9.2 Conjugated Polymers as Binder Materials in LIBs
9.3 Conjugated Polymers as Anodic Materials
9.4 Polymerizable Conjugated Molecules as Electrolyte additives
9.5 Pi-Conjugated Polymers as Electrocatalysts
9.6 Conclusion
 
10 CONJUGATED POLYMERS AND THEIR APPLICATIONS IN ORGANIC FIELD EFFECT TRANSISTOR, ORGANIC ELECTROCHEMICAL TRANSISTORS, AND ORGANIC THERMOELECTRICS
10.1 Introduction
10.2 Polymers for Organic Field Effect Transistors
10.3 Organic Electrochemical Transistors (OECTs)
10.4 Organic Thermoelectrics (OTEs)
 
11 PI-CONJUGATED POLYMERS WITH CONTROLLED HIGHER-ORDER STRUCTURES: POLY(ACETYLENE)S AND POLY(ARYLENEETHYNYLENE)S
11.1 Introduction
11.2 Helical Substituted Poly(acetylene)s
11.3 Poly(aryleneethynylene)s
11.4 Platinum-Containing Poly(aryleneethynylene)s
11.5 Summary and Outlook
 
12 ADVANCES IN ORGANIC SOLAR CELL PERFORMANCE INVOLVING ANTHRACENE AND ANTHANTHRONE CORE POLYCYCLIC AROMATIC MATERIALS
12.1 Introduction
12.2 Anthracene-Containing Materials for OSCs Applications
12.3 Anthanthrone-Containing Materials for OSCs Applications
12.4 Hole Transporting Materials
12.5 Conclusions
 
13 CONJUGATED POLYMERS FOR BIOMEDICAL APPLICATIONS
13.1 Introduction
13.2 Biosensing and Biological Detection
13.3 Biological Imaging
13.4 Therapeutic Applications
13.5 Conclusions
 
Index

Über Autor(innen)

Yoshiki Chujo, Professor Emeritus, Kyoto University, Japan Yoshiki Chujo completed his Ph.D. at Kyoto University in 1980 and then joined Nagoya University as an Assistant Professor in 1981. In 1986, he returned to Kyoto University as a Lecturer, and was promoted as a Professor of Polymer Chemistry there since 1994. His research interests focus on polymer synthesis, inorganic polymers, and polymeric hybrid materials. Prof. Chujo has been working as a Project Leader of the MEXT Scientific Research on Innovative Areas ?New Polymeric Materials Based on Element-Blocks?, Japan during 2012-2017. He retired from Kyoto University in 2018, and now is a Professor Emeritus of Kyoto University, together with a Guest Professor of Ritsumeikan University, Japan. Prof. Chujo has received the purple ribbon medal from the Emperor of Japan in recognition of his academic accomplishments.