Buch, Englisch, 382 Seiten, Format (B × H): 152 mm x 229 mm, Gewicht: 583 g
Buch, Englisch, 382 Seiten, Format (B × H): 152 mm x 229 mm, Gewicht: 583 g
Reihe: Physical Methods in Organic Chemistry
ISBN: 978-1-4684-1787-6
Verlag: Springer US
In recent years high-resolution nuclear magnetic resonance spec troscopy has found very wide application in organie chemistry in structural and physicochemical investigations and. also in the study of the characteristics of organic compounds which are re lated to the distribution of the electron cloud in the molecules. The vigorous development of this method, which may really be re garded as an independent branch of science, is the result of ex tensive progress in NMR technology, the refinement of its theory, and the accumulation of large amounts of experimental material, which has been correlated by empiricallaws and principles. The literature directly concerned with the NMR method and its applica tion has now grown to such an extent that a complete review of it is practically impossible. Therefore the authors have limited themselves to an examination of only the most important, funda mental, and general investigations. The book consists of six chapters. In the first chapter we have attempted to present the fundamentals of the NMR method in such a way that the reader with little knowledge of the subject will be able to use the method in practical work for investigating simple compounds and solving simple problems. The three subsequent chapters give a deeper analysis of the method, while the last two chapters and the appendix illustrate the various applications of NMR spectroscopy in organic chemistry.
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I. The Fundamentals of NMR Spectroscopy.- 1. Magnetic properties of matter. Nuclear moments Nuclear resonance.- 2. Observation of nuclear magnetic resonance.- 3. Spin-lattice relaxation.- 4. Line width in NMR spectra.- 5. Saturation.- 6. Rate of sweep of spectrum.- 7. Main parameters of NMR spectra.- 8. Some features of high-resolution NMR spectra.- 9. High-resolution NMR spectrometers.- 10. Scope and limits of applicability of the NMR method.- 11. Indexing of NMR spectra.- 12. Manuals and textbooks on nuclear magnetic resonance.- Literature Cited.- II. Chemical Shift.- A. Proton Chemical Shifts.- 4. Molecular component of magnetic screening ?M.- B. Chemical Shifts of Nuclei of Other Magnetic Isotopes.- III. Spin — Spin Coupling.- 1. Spin—spin coupling between geminal protons.- 2. Spin—spin coupling between vicinal protons.- 3. Spin—spin coupling between remote protons (long-range coupling).- 4. H1 —C13 spin—spin coupling.- 5. Spin-spin coupling with the nucleus F19.- 6. Spin—spin coupling between fluorine nuclei Jff.- 7. Spin—spin coupling of protons and fluorine with magnetic nuclei of Group IV B elements.- 8. Spin—spin coupling involving P31 nuclei.- 9. Spin—spin coupling of protons and fluorine with other magnetic nuclei.- Literature Cited.- IV. Analysis of Complex Nuclear Magnetic Resonance Spectra.- A. Complete Analysis o f Spectra of Complex Systems of Nuclear Spins.- B Nuclear Magnetic Double Resonance.- V. NMR Spectra and the Structure of Organic Molecules.- 1. Saturated hydrocarbons with an open chain and their functional derivatives containing no protons directly attached to heteroatoms.- 3. Olefinic and Acetylenic Compounds.- 4. Aromatic hydrocarbons and heterocycles.- 5. NMR spectra of compounds with proton-containing functionalgroups.- 6. Compounds containing atoms of fluorine, phosphorus, and other magnetic nuclei.- Literature Cited.- VI. Application of NMR Spectroscopy in Various Fields of Organic Chemistry.- 1. Intermediate reaction products and complexes.- 2. Kinetics and mechanism of organic reactions.- 3. Kinetics of exchange processes.- 4. Tautomerism and valence isomerism.- 5. Compounds containing an unpaired electron.- Literature Cited.
