Buch, Englisch, 720 Seiten, Format (B × H): 187 mm x 256 mm, Gewicht: 1280 g
A Practical Design Approach
Buch, Englisch, 720 Seiten, Format (B × H): 187 mm x 256 mm, Gewicht: 1280 g
ISBN: 978-1-394-16412-7
Verlag: Wiley
The first textbook to fully integrate Green and Sustainable Chemistry and Engineering, now in its second edition
Green and Sustainable Chemistry and Engineering addresses key concepts and processes from an industrial and manufacturing perspective. Using an integrated, systems-oriented approach, this invaluable single-volume resource bridges the divide between chemistry, process design, and engineering, as well as environment, health, safety, and life cycle considerations.
This revised new edition discusses trends in chemical processing that can lead to more sustainable practices, explores new methods in the design of greener chemical synthesis, addresses sustainability challenges and implementation issues, and more. Up-to-date examples and new practical exercises based on the broad experience of the authors in applied and fundamental research, corporate consulting, and education are incorporated throughout the text.
Designed to advance green chemistry and green engineering as disciplines in the broader context of sustainability, Green and Sustainable Chemistry and Engineering: - Illustrates the role of green and sustainable chemistry and engineering in the adoption of sustainable practices
- Describes the components of chemistry supporting the design of sustainable chemical reactions and reaction pathways
- Presents an approach to materials selection promoting the sustainability of chemical synthesis without diminishing efficiency
- Highlights key concepts that support the design of more sustainable chemical processes
- Provides background and context for placing a particular chemical process in the broader chemical enterprise
- Includes access to a companion website with a solutions manual and supplementary resources
Green and Sustainable Chemistry and Engineering: A Practical Design Approach, Second Edition, remains an ideal textbook for graduate and senior-level courses in Chemistry and Chemical Engineering, and an invaluable reference for chemists and engineers in manufacturing and R&D, especially those working in fine chemicals and pharmaceuticals.
Autoren/Hrsg.
Fachgebiete
- Geowissenschaften Umweltwissenschaften Umweltschutz, Umwelterhaltung
- Technische Wissenschaften Umwelttechnik | Umwelttechnologie Umwelttechnik
- Technische Wissenschaften Verfahrenstechnik | Chemieingenieurwesen | Biotechnologie Chemische Verfahrenstechnik
- Naturwissenschaften Chemie Analytische Chemie Umweltchemie, Lebensmittelchemie
Weitere Infos & Material
List of Figures xi
About the Authors xix
Preface xxi
Acknowledgments xxiii
About the Companion Website xxv
Part I Green and Sustainable Chemistry and Engineering In the Movement Toward Sustainability 1
1 Green Chemistry and Engineering in the Context of Sustainability 3
1.1 Why Green Chemistry? 3
1.2 Green Chemistry, Green Engineering, and Sustainability 6
1.3 Until Death Do Us Part: A Marriage of Disciplines 11
2 Green Chemistry and Green Engineering Principles 15
2.1 Green Chemistry Principles 15
2.2 Twelve More Green Chemistry Principles 24
2.3 Twelve Principles of Green Engineering 26
2.4 The San Destin Declaration: Principles of Green Engineering 30
2.5 Simplifying Green Chemistry and Engineering Principles 32
2.6 Additional Principles 33
3 Starting With The Basics: Integrating Environment, Health, and Safety 41
3.1 Environmental Issues of Importance 42
3.2 Health Issues of Importance 53
3.3 Safety Issues of Importance 62
3.4 Hazard and Risk 69
3.5 Integrated Perspective on Environment, Health, and Safety 71
4 How Do We Know It’s Green? a Metrics Primer 79
4.1 General Considerations About Green Chemistry and Engineering Metrics 79
4.2 Chemistry Metrics 81
4.3 Process Metrics 91
4.4 Cost Implications and Green Chemistry Metrics 104
4.5 Thoughts on Circularity 104
4.6 A Final Word on Green Metrics 107
5 Systems Thinking Essentials for More Sustainable Chemistry and Engineering 113
5.1 Systems Thinking in Chemistry 113
5.2 Where Systems Thinking Fits 114
5.3 A Systems Thinking Example 118
5.4 Systems and Life Cycle Thinking Background 118
5.5 Application of Green and Sustainable Chemistry Thinking to the System 123
5.6 Some Thoughts About Sustainable Chemistry 123
5.7 Glossary of Systems Thinking Terms 125
Part II the Beginning: Designing Greener, Safer, More Sustainable Chemical Syntheses 133
6 Route and Chemistry Selection 135
6.1 The Challenge of Synthetic Chemistry 135
6.2 Making Molecules 136
6.3 Using Different Chemistries 145
6.4 Route Strategy 148
6.5 Protection– Deprotection 150
6.6 Going From A Route to a Process 152
6.7 Additional Tools for Greener Route and Process Design 153
7 Material Selection: Solvents, Catalysts, and Reagents 159
7.1 Solvents and Solvent Selection Strategies 159
7.2 Catalysts and Catalyst Selection Strategies 180
7.3 Other Reagents 194
8 Reaction Conditions and Green Chemistry 203
8.1 Stoichiometry 204
8.2 Design of Experiments 206
8.3 Temperature 208
8.4 Solvent Use 210
8.5 Solvents and Energy Use 212
8.6 Reaction and Processing Time 215
8.7 Order and Rate of Reagent Addition 216
8.8 Mixing 217
9 Bioprocesses 231
9.1 How Biotechnology Has Been Used 231
9.2 Are Bioprocesses Green? 232
9.3 What Is Involved in Bioprocessing 233
9.4 Examples of Products Obtained From Bioprocessing 243
Part III From the Flask to the Plant: Designing Greener, Safer, More Sustainable Manufacturing Processes 265
10 Mass and Energy Balances 267
10.1 Why We Need Mass Balances, Energy Balances, and Process Flow Diagrams 268
10.2 Types of Processes 269
10.3 Process Flow Diagrams 270
10.4 Mass Balances 273
10.5 Energy Balances 282
10.6 Measuring Greenness of a Process Through Energy and Mass Balances 294
11 The Scale- Up Effect 305
11.1 The Scale- Up Problem 305
11.2 Factors Affecting Scale- Up 308
11.3 Scale- Up Tools 315
11.4 Numbering- Up Vs. Scaling- Up 320
12 Reactors and Separations 327
12.1 Reactors and Separations in Green Engineering 328
12.2 Reactors 328
12.3 Separations and Other Unit Operations 338
12.4 Batch Vs. Continuous Processes 352
12.5 Process Intensification: Does Size Matter? 354
13 Process Synthesis 383
13.1 Process Synthesis Background 383
13.2 Process Synthesis Approaches and Green Engineering 385
13.3 Evolutionary Techniques 386
13.4 Heuristics Methods 395
13.5 Hierarchical Decomposition 397
13.6 Superstructure and Multiobjective Optimization 400
13.7 Synthesis of Subsystems 405
13.8 Process Synthesis Applied to Circular Economy 406
14 Mass and Energy Integration 415
14.1 Process Integration: Synthesis, Analysis, and Optimization 415
14.2 Energy Integration 417
14.3 Mass Integration 425
15 Inherent Safety 443
15.1 Inherent Safety Vs. Traditional Process Safety 443
15.2 Inherent Safety and Inherently Safer Design 446
15.3 Inherent Safety in Route Strategy and Process Design 450
15.4 Conclusions on Inherent Safety 458
Part IV Expanding the Boundaries 465
16 Life Cycle Inventory and Assessment Concepts 467
16.1 Life Cycle Inventory and Assessment Background 468
16.2 LCI/A Methodology 470
16.3 Interpretation: Making Decisions With LCI/A 494
16.4 Streamlined Life Cycle Assessment 506
17 Impacts of Materials and Procurement 519
17.1 Life Cycle Management 519
17.2 Where Chemical Trees and Supply Chains Come From 521
17.3 Green (Sustainable) Procurement 529
17.4 Transportation Impacts 536
18 Impacts of Energy Requirements 545
18.1 Where Energy Comes From 545
18.2 Environmental Life Cycle Emissions and Impacts of Energy Generation 551
18.3 From Emissions to Impacts 563
18.4 Energy Requirements for Waste Treatment 565
19 Impacts of Waste and Waste Treatment 569
19.1 Environmental Fate and Effects Data 569
19.2 Environmental Fate Information: Physical Properties 574
19.3 Environmental Fate Information: Transformation and Depletion Mechanisms 581
19.4 Environmental Effects Information 583
19.5 Environmental Risk Assessment 586
19.6 Environmental Life Cycle Impacts of Waste Treatment 589
20 Evaluating Technologies 603
20.1 Why We Need to Evaluate Technologies and Processes Comprehensively 603
20.2 Comparing Technologies and Processes 604
20.3 One Way to Compare Technologies 605
20.4 Trade- offs 612
20.5 Advantages and Limitations of Comparing Technologies 613
Part V What Lies Ahead 619
21 Design for Circularity 621
21.1 Industrial Ecology Background 622
21.2 Principles and Concepts of Industrial Ecology, Circularity, and Design 626
21.3 Industrial Ecology and Circularity by Design 629
21.4 Industrial Ecology and Circularity in Practice 634
22 Renewable Resources 639
22.1 Why We Need Renewable Resources 639
22.2 Renewable Materials 642
22.3 The Biorefinery 646
22.4 Renewable Energy 654
23 Tying It All Together: Is Sustainability Possible? 665
23.1 How Might Green and Sustainable Chemistry and Engineering Enable Sustainability? 666
23.2 Sustainability: Culture and Policy 667
23.3 Influencing Sustainability 668
23.4 Moving to Action 670
Problems 671
References 671
Index 673
