Thermal Decomposition of Solids and Melts

New Thermochemical Approach to the Mechanism, Kinetics and Methodology
2007
ISBN: 978-1-4020-5671-0
Verlag: Springer Netherlands

Buch, Englisch, 247 Seiten, Format (B × H): 160 mm x 241 mm, Gewicht: 571 g

Reihe: Hot Topics in Thermal Analysis and Calorimetry

The appearance of this English edition of my book, ?rst published in Russian in mid-2006, is related to the help and support of two prominent scientists: Professor Michael Brown (Rhodes University Grahamstown, South Africa) and Dr. Judit Simon (Budapest University of Technology and Economics, Hungary). The story is as follows. In the winter of 2006, in the process of exchange of views by email with Michael on some problems of decomposition kinetics, I asked him about the possibility of publishing my book in English. He s- gestedthatIshouldcontactJudit,theSeriesEditorof“HotTopicsinThermal Analysis and Calorimetry”. My application was kindly accepted, considered, and approved. As a result, Judit strongly recommended this book to Springer for publication, and Michael kindly agreed to help me with linguistic impro- ments of my hurriedly translated book. In the process of editing, he made some critical comments and questions, which stimulated me to improve and clarify the text, but we did have to agree to put our di?erences of scienti?c opinions aside so as not to delay the process. Without this invaluable help, this book would not be as “readable” as I hope it is now. The author uses this opportunity to express his sincere thanks to Michael and Judit for their signi?cant help and support. Although only about a year has gone after the preparation of the original edition of the book (in Russian), this English version of the manuscript has undergone considerable revision. These changes refer to Sections2. 2, 2.

Zielgruppe

Research

Autoren/Hrsg.

L'Vov, Boris V.

Fachgebiete

• Technische Wissenschaften Maschinenbau | Werkstoffkunde Technische Mechanik | Werkstoffkunde Materialwissenschaft: Keramik, Glas, Sonstige Werkstoffe
• Technische Wissenschaften Technik Allgemein Nanotechnologie
• Naturwissenschaften Physik Quantenphysik
• Naturwissenschaften Chemie Physikalische Chemie Thermochemie, Chemische Thermodynamik
• Technische Wissenschaften Maschinenbau | Werkstoffkunde Technische Mechanik | Werkstoffkunde Werkstoffprüfung
• Naturwissenschaften Physik Thermodynamik Festkörperphysik, Kondensierte Materie
• Naturwissenschaften Chemie Analytische Chemie
• Technische Wissenschaften Maschinenbau | Werkstoffkunde Technische Mechanik | Werkstoffkunde Materialwissenschaft: Verbundwerkstoffe
• Technische Wissenschaften Maschinenbau | Werkstoffkunde Technische Mechanik | Werkstoffkunde Werkstoffkunde, Materialwissenschaft: Forschungsmethoden

Inhaltsverzeichnis

Thermal Decomposition: Basic Concepts.- Historical Overview.- Decomposition Mechanism.- Decomposition Kinetics.- Methodology.- Interpretation and Quantitative Analysis of the Effects and Phenomena Accompanying Thermal Decomposition.- Decomposition Conditions and the Molar Enthalpy.- The Self-cooling Effect.- The Topley–Smith Effect.- Impact of Vapour Condensation on the Reaction Enthalpy.- Thermochemical Analysis of the Composition of the Primary Products.- Effect of the Reactant Crystal Structure on the Composition of the Primary Decomposition Products.- Vaporization Coefficients.- The Kinetic Compensation Effect.- Conclusions.- Thermal Decomposition of Individual Substances.- Instruments for Thermogravimetric Measurements.- Measurement Conditions and Procedures for Isothermal Thermogravimetric Studies.- Sublimation and Decomposition Reactions.- Final Remarks.

Über Autor(innen)

Professor and Head of the Analytical Chemistry department at St. Petersburg State University, Russia.