Maeda / Takahara / Kitano Molecular Soft-Interface Science

Principles, Molecular Design, Characterization and Application
1. Auflage 2019
ISBN: 978-4-431-56877-3
Verlag: Springer Japan
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 219 Seiten

This book offers a comprehensive treatment of the molecular design, characterization, and physical chemistry of soft interfaces. At the same time, the book aims to encourage the fabrication of functional materials including biomaterials. During the past few decades there has been steady growth in soft-interface science, and that growth has been especially rapid in the twenty-first century. The field is interdisciplinary because it involves chemistry, polymer science, materials science, physical chemistry, and biology. Based on the increasing interdisciplinary nature of undergraduate and graduate programs, the primary goal of this present work is to serve as a comprehensive resource for senior-level undergraduates and for graduate students, particularly in polymer chemistry, materials science, bioconjugate chemistry, bioengineering, and biomaterials. Additionally, with the growing interest in the fabrication of functional soft materials, this book provides essential fundamental information for researchers not only in academia but also in industry.

Mizuo Maeda Mizuo Maeda received his Ph.D. from the University of Tokyo (1983). He was a full professor of materials physics and chemistry at Kyushu University before moving to RIKEN Institute as a chief scientist and a director of Bioengineering Laboratory. His research interests center on polymer chemistry, analytical chemistry, and biomaterials science.   Atsushi Takahara Atsushi Takahara earned his D.Eng. (1983) in the field of polymer science. Since 1999, he is a full professor of Kyushu University. His research interests are focused on advanced soft materials such as polymer ultrathin films, polymer nanocomposites, and novel tough polymers.     Hiromi KitanoHiromi Kitano is a director of the Institute for Polymer-Water Interfaces (Toyama, Japan). He earned his Dr. Eng. in Kyoto University (1980). He was a full professor of University of Toyama from 1992 to 2016. His research interests are focused on the structure analyses of water in the vicinity of polymer materials, development and application of biocompatible polymers, and analyses of molecular recognition processes at the interfaces of water-polymer materials.    Tetsuji YAMAOKA Tetsuji YAMAOKA is a director of Department of Biomedical Engineering of National Cerebral and Cardiovascular Center Research Institute (Osaka Japan).   He earned his Dr. Eng. in Kyoto University (1993). He is a Fellow of Biomaterials Science and Engineering (FBSE) and Japanese Delegate of the International Union of Societies for Biomaterials Science and Engineering. His research interests are cardiovascular artificial organs, regenerative medicines, and molecular imaging.   Yoshiko Miura Yoshiko Miura is a Professor at Kyusyu University. She received her B. Eng. Degree in 1995, M. Eng. Degree in 1997, and Dr. Eng. Degree in 2000 from the Kyoto University. She was appointed Assistant Professor at Nagoya University in 2001, Associate Professor at JAIST in 2005, and Professor at Kyushu University in 2010. Her research interests are biomaterial fabrication with glycopolymers and glyco-nanoparticles.

Autoren/Hrsg.

Maeda, Mizuo

Takahara, Atsushi

Kitano, Hiromi

Yamaoka, Tetsuji

Miura, Yoshiko

Inhaltsverzeichnis

1;Preface;5
2;Contents;7
3;The Principle and Physical Chemistry of Soft Interface;9
4;1 The Principle and Physical Chemistry of Soft Interface;10
4.1;1.1 Colloid and Interface (Molecular Force, Colloid, Air/Water Interface);10
4.1.1;1.1.1 Molecular Force;10
4.1.2;1.1.2 Colloid;12
4.1.3;1.1.3 Stability of Colloid;12
4.1.4;1.1.4 Surface Adsorption;16
4.2;1.2 Wettability and Molecular Science;19
4.2.1;1.2.1 Surface Tension;19
4.2.2;1.2.2 Wettability;21
4.3;1.3 Surfactants (Structure and Function, Emulsion);23
4.3.1;1.3.1 Surfactants;23
4.3.2;1.3.2 Surfactant-Stabilized Soft Dispersed Systems;27
4.4;References;30
5;Design of Soft Interface (Synthesis and Processing);33
6;2 Molecular Design of Soft Interface;34
6.1;2.1 Polymerization Method;34
6.2;2.2 Iniferter;36
6.3;2.3 Stable Free Radical Polymerization (NMP);37
6.4;2.4 Atom Transfer Radical Polymerization (ATRP);40
6.5;2.5 Reversible Addition-Fragmentation Chain Transfer (RAFT) Radical Polymerization;42
6.6;2.6 Organotellulium-Mediated Living Radical Polymerization (TERP);46
6.7;2.7 Block Copolymers;48
6.8;2.8 Graft Copolymers;51
6.9;2.9 Hydrophobically Modified Polyelectrolytes (Random Copolymers);53
6.10;2.10 Gels;54
6.11;References;55
7;3 Nano- and Micro-technology of Soft Interface;60
7.1;3.1 Supramolecular Formation;60
7.1.1;3.1.1 Supramolecular Formation with Biomacromolecules;60
7.1.2;3.1.2 Supramolecular Nanomaterials;61
7.1.3;3.1.3 Langmuir and Langmuir–Blodgett Membranes;63
7.1.4;3.1.4 Self-assembled Monolayer (SAM);65
7.1.5;3.1.5 Alternate Layer-by-Layer Assembly (LBL);66
7.1.6;3.1.6 Polymers with Special Structure;68
7.1.7;3.1.7 Hyperbranched Polymers;71
7.1.8;3.1.8 Polyrotaxane;72
7.2;3.2 Nano- and Microfabrication of Soft Interface;73
7.2.1;3.2.1 Intelligent Soft Interfaces for Biology;73
7.3;References;77
8;Characterization and Physical Properties of Soft Interface;80
9;4 Infrared and Raman Spectroscopy for Thin-Film Analysis;81
9.1;4.1 Infrared Spectroscopy;81
9.2;4.2 Raman Spectroscopy;86
9.3;References;88
10;5 Sum Frequency Generation (SFG);90
10.1;5.1 Introduction;90
10.2;5.2 Principle;90
10.3;5.3 Peak Assignments [11];92
10.4;5.4 Orientation of Functional Groups;93
10.4.1;5.4.1 PMMA/N2 Interface;94
10.4.2;5.4.2 PMMA/Water Interface;96
10.4.3;5.4.3 Water Structure at the PMMA Interface;99
10.5;5.5 Conclusions;100
10.6;References;100
11;6 Surface Analysis;103
11.1;6.1 X-Ray Photoelectron Spectroscopy (XPS);103
11.1.1;6.1.1 Introduction;103
11.1.2;6.1.2 Surface Segregation in Polymer Blends [1];104
11.1.3;6.1.3 Chain End Segregation in Polymer Blends [6];108
11.1.4;6.1.4 Summary;109
11.2;6.2 Secondary Ion Mass Spectroscopy (SIMS);109
11.2.1;6.2.1 Introduction;109
11.2.2;6.2.2 Surface Composition in an Isotopic Polymer Blend (SSIMS) [11];110
11.2.3;6.2.3 Mobility Gradient Near Polymer Surfaces (DSIMS) [13];111
11.2.4;6.2.4 Summary;115
11.3;References;115
12;7 Scattering and Reflection;117
12.1;7.1 Static and Dynamic Light Scattering (SLS, DLS);117
12.2;7.2 Small-Angle X-Ray and Neutron Scattering (SAXS, SANS);123
12.3;References;128
13;8 X-Ray and Neutron Reflectivity and Grazing Incidence X-Ray Diffraction;130
13.1;8.1 Background;130
13.2;8.2 Reflectivity;132
13.3;8.3 Example of Reflectivity from Thin Films;134
13.4;8.4 Grazing Incidence Wide-Angle X-Ray Diffraction;138
13.5;8.5 Conclusions and Perspective;138
13.6;References;140
14;9 Scanning Electron Microscopy;141
14.1;9.1 Introduction;141
14.2;9.2 Basic Components of SEM;142
14.3;9.3 Various Information Obtainable in SEM;142
14.4;9.4 A New Type of SEM—Atmospheric SEM;144
14.5;References;146
15;10 Transmission Electron Microscopy;147
15.1;10.1 Introduction;147
15.2;10.2 Basic Components of TEM;148
15.3;10.3 Various Modes in TEM Observations;150
15.4;10.4 An Example of Visualization of Soft Interface by TEM;152
15.5;References;153
16;11 Scanning Probe Microscopy (SPM);154
16.1;11.1 Introduction;154
16.2;11.2 Scanning Tunneling Microscopy (STM);155
16.3;11.3 Atomic Force Microscopy (AFM);157
16.4;11.4 Other Scanning Probe Techniques;161
16.5;References;162
17;Application of Soft Interface;164
18;12 High-Performance Interface;165
18.1;12.1 Polymer Brush;165
18.2;12.2 Wettability and Antifouling;166
18.3;12.3 Adhesion;168
18.4;12.4 Friction and Lubrication;170
18.5;12.5 Conclusions;173
18.6;References;174
19;13 Bio- and Chemical Sensors and Role of Soft Interface;179
19.1;13.1 Bio- and Chemical Sensors and Soft Interfaces (Introduction);179
19.2;13.2 Methodology of Sensing/Biosensing— Electrochemistry, QCM, SPR, and FET;183
19.2.1;13.2.1 Quartz Crystal Microbalance (QCM);183
19.2.2;13.2.2 Surface Plasmon Resonance (SPR) Measurement;186
19.2.3;13.2.3 Electrochemistry;188
19.2.4;13.2.4 Field-Effect Transistors (FETs);189
19.3;13.3 Biosensing by Various Methods;191
19.3.1;13.3.1 QCM Measurements;191
19.3.2;13.3.2 Surface Plasmon Resonance Measurements;191
19.3.3;13.3.3 Electrochemical Methods;193
19.3.4;13.3.4 Field-Effect Transistors (FETs);194
19.4;References;195
20;14 Nonprotein-Fouling, Hemocompatible, and Biospecific Surfaces Generated with Phospholipid Polymers;197
20.1;14.1 General Background of Protein Adsorption;197
20.2;14.2 Design of Phosphorylcholine-Bearing Polymers;198
20.3;14.3 Mechanism of Nonprotein Fouling on MPC Polymer Surfaces;199
20.4;14.4 Hemocompatibility of MPC Polymers;200
20.5;14.5 Regulation of Specific Molecular Interactions on MPC Polymer Surfaces;202
20.5.1;14.5.1 Protein-Conjugated Surfaces;202
20.5.2;14.5.2 Protein-Imprinted Surfaces;203
20.5.3;14.5.3 Carbohydrate-Bearing Surfaces;204
20.6;14.6 Conclusion;205
20.7;References;205
21;15 Stem Cell Purification on a Cell-Compatible, Cell-Specific Biointerface;208
21.1;15.1 Introduction;208
21.2;15.2 Stem Cell Separation;210
21.3;15.3 Cell Rolling Mechanisms;212
21.4;15.4 Cell Separation on Ligand-Immobilized Column;212
21.5;15.5 Mesenchymal Stem Cells Separation;215
21.6;15.6 Conclusion;216
21.7;References;218