Molander / Fürstner Science of Synthesis: Stereoselective Synthesis Vol. 2

Stereoselective Reactions of Carbonyl and Imino Groups
1. Auflage 2014
ISBN: 978-3-13-178941-9
Verlag: Thieme
Format: PDF
Kopierschutz: Adobe DRM (»Systemvoraussetzungen)

E-Book, Englisch, 1061 Seiten, PDF, Format (B × H): 170 mm x 240 mm

Reihe: Science of Synthesis

Carbonyl and imino groups are two of the most integral functional groups employed in organic synthesis. Specific topics discussed: reduction, alkylation, alkenylation, and arylation of these groups, as well as asymmetric aldol, Mannich, and Morita-Bayliss-Hillman reactions.

This volume is part of a 3-volume set:

Further information about Stereoselective Synthesis (including sample pages and the table of contents)

Zielgruppe

Wissenschaftler

Autoren/Hrsg.

Fürstner, Alois

Molander, Gary A.

Fachgebiete

• Naturwissenschaften Chemie Organische Chemie

Inhaltsverzeichnis

2.1 Reduction of Carbonyl Groups: Hydrogenation
2.2 Reduction of Carbonyl Groups: Transfer Hydrogenation, Hydrosilylation, Catalytic Hydroboration, and Reduction with Borohydrides, Aluminum Hydrides, or Boranes
2.3 Enzymatic Reduction of Carbonyl Groups
2.4 Oxidative Deracemization
2.5 Stereoselective Reduction of Imino Groups
2.6 Epoxidation and Aziridination of Carbonyl Groups and Imines
2.7 Alkylation of Carbonyl and Imino Groups
2.8 Allylation of Carbonyl and Imino Groups
2.9 Arylation and Alkenylation of Carbonyl and Imino Groups
2.10.1 Enantioselective Addition of Acetylide Nucleophiles to Carbonyl Compounds
2.10.2 Enantioselective Addition of Metal Alkynylides to Imino Groups
2.11 Hydrocyanation, Cyanosilylation, and Hydrophosphonylation of Carbonyl and Imino Groups
2.12 Asymmetric Mukaiyama Aldol Reaction
2.13 Direct Aldol Reactions
2.14 Enzymatic Direct Aldol Additions
2.15 Asymmetric Morita–Baylis–Hillman Reaction and Its Aza Analogue
2.16 Mannich Reaction
2.17 Asymmetric Benzoin and Stetter Reactions
2.18 Asymmetric Synthesis of Spiroketals, Bisspiroketals, and Spiroaminals