Probstein / Brenner Physicochemical Hydrodynamics

An Introduction
1. Auflage 2013
ISBN: 978-1-4831-6222-5
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 368 Seiten, Web PDF

Physicochemical Hydrodynamics: An Introduction aims to provide an introduction to physicochemical hydrodynamics (PCH), which deals with the interaction between fluid flow and physical, chemical, and biochemical processes. PCH has applications in many areas of science and technology and is a rapidly expanding field. Emphasis of this book is on rational theory and its consequences, with the purpose of showing the underlying unity of PCH, in which diverse phenomena can be described in physically and mathematically similar ways. The magic of this unity is shown in the similar manner in which solutes concentrate in a flow containing chemically reacting surfaces, reverse osmosis membranes, and electrodialysis membranes or the similarity of particle motions in sedimentation, centrifugation, ultrafiltration, and electrophoresis. Problems are included at the end of each chapter and are ordered following the sequence in which the material is set out. The questions range in difficulty, with most requiring an analytic development, but with some asking only for a descriptive answer. All problems are intended to illustrate the ideas presented, though often the solution goes beyond the explicit discussion in the book, with the answer constituting a generalization or extension of the text material. This book is an essential source of information for students majoring in the field of PCH.

Autoren/Hrsg.

Probstein, Ronald F.

Brenner, Howard

Inhaltsverzeichnis

1;Front Cover;1
2;Physicochemical Hydrodynamics: An Introduction;4
3;Copyright Page;5
4;Table of Contents;8
5;Dedication;6
6;Preface;12
7;Acknowledgments;14
8;Chapter 1. Introduction;16
8.1;1.1 Physicochemical Hydrodynamics;16
8.2;1.2 Fluid and Flow Approximations;17
8.3;1.3 Particle and Pore Geometry;18
8.4;References;23
9;Chapter 2. Transport in Fluids;24
9.1;2.1 Phenomenological Models;24
9.2;2.2 Viscosity and Momentum Transport;25
9.3;2.3 Thermal Conductivity and Heat Transport;32
9.4;2.4 Diffusivity and Mass Transport;36
9.5;2.5 Electrical Conductivity and Charge Transport;41
9.6;References;44
9.7;Problems;44
10;Chapter 3. Equations of Change;46
10.1;3.1 Isothermal;46
10.2;3.2 Nonisothermal;49
10.3;3.3 Multicomponent;52
10.4;3.4 Charged Species;56
10.5;3.5 Characteristic Parameters;60
10.6;References;65
10.7;Problems;65
11;Chapter 4. Solutions of Uncharged Molecules;68
11.1;4.1 Diffusion and Reaction Kinetics;68
11.2;4.2 Convective Diffusion Layer Characteristics;74
11.3;4.3 Channel Flow with Soluble or Rapidly Reacting Walls;79
11.4;4.4 Reverse Osmosis and Mixed Heterogeneous Reactions;83
11.5;4.5 Flow Past a Reacting Flat Plate;93
11.6;Taylor Dispersion in a Capillary Tube;96
11.7;4.6 Taylor Dispersion in a Capillary Tube;96
11.8;4.7 Gel Chromatography and Capillary Models of Porous Media;111
11.9;References;117
11.10;Problems;118
12;Chapter 5. Solutions of Uncharged Macromolecules and Particles;122
12.1;5.1 Microhydrodynamics of Macromolecules and Particles;122
12.2;5.2 Brownian Motion;129
12.3;5.3 Viscosity of Dilute Suspensions;136
12.4;5.4 Sedimentation under Gravity;144
12.5;5.5 Sedimentation in a Centrifugal Field;156
12.6;5.6 Ultrafiltration;167
12.7;References;172
12.8;Problems;173
13;Chapter 6. Solutions of Electrolytes;176
13.1;6.1 The Electrolytic Cell;176
13.2;6.2 Electrodialysis;185
13.3;6.3 Ion Exchange;193
13.4;6.4 The Electric Double Layer and Electrokinetic Phenomena;200
13.5;6.5 Electroosmosis;206
13.6;References;213
13.7;Problems;214
14;Chapter 7. Solutions of Charged Macromolecules and Particles;216
14.1;7.1 The Charge of Macromolecules and Particles;216
14.2;7.2 Electrophoresis;219
14.3;7.3 Electrophoretic Separations;228
14.4;7.4 Sedimentation Potential and Streaming Potential;235
14.5;References;237
14.6;Problems;238
15;Chapter 8. Suspension Stability and Particle Capture;242
15.1;8.1 Colloid Stability;242
15.2;8.2 Brownian and Velocity Gradient Flocculation;251
15.3;8.3 Particle Capture by Brownian Diffusion and Interception;256
15.4;8.4 Particle Capture with Surface Forces;264
15.5;8.5 Filtration and Drag Models of Porous Media;272
15.6;References;278
15.7;Problems;279
16;Chapter 9. Surface Tension;282
16.1;9.1 Physics of Surface Tension;282
16.2;9.2 Capillarity and Capillary Motion;291
16.3;9.3 Coating Flows;295
16.4;9.4 Surface Waves and Jet Breakup;304
16.5;9.5 Flows Driven by Surface Tension Gradients;315
16.6;References;329
16.7;Problems;330
17;Appendix A: SI Units and Physical Constants;334
17.1;SI Base Units;334
17.2;SI Derived Units;334
17.3;SI Prefixes;335
17.4;Physical Constants;335
18;Appendix B: Symbols;336
19;Author Index;348
20;Subject Index;352