Fundamentals of Conjugated Polymer Blends, Copolymers and Composites

1. Auflage 2015
ISBN: 978-1-118-54949-0
Verlag: John Wiley & Sons

Buch, Englisch, 800 Seiten, Format (B × H): 161 mm x 240 mm, Gewicht: 1232 g

Since their discovery in 1977, the evolution of conducting polymers has revolutionized modern science and technology. These polymers enjoy a special status in the area of materials science yet they are not as popular among young readers or common people when compared to other materials like metals, paper, plastics, rubber, textiles, ceramics and composites like concrete. Most importantly, much of the available literature in the form of papers, specific review articles and books is targeted either at advanced readers (scientists / technologists / engineers / senior academicians) or for those who are already familiar with the topic (doctoral / postdoctoral scholars). For a beginner or even school / college students, such compilations are bit difficult to access / digest. In fact, they need proper introduction to the topic of conducting polymers including their discovery, preparation, properties, applications and societal impact, using suitable examples and already known principles/knowledge/phenomenon.

Further, active participation of readers in terms of "question & answers", "fill-in-the-blanks", "numerical" along with suitable answer key is necessary to maintain the interest and to initiate the "thought process". The readers also need to know about the drawbacks and any hazards of such materials. Therefore, I believe that a comprehensive source on the science / technology of conducting polymers which maintains a link between grass root fundamentals and state-of-the-art R&D is still missing from the open literature.

Autoren/Hrsg.

Saini, Parveen

Fachgebiete

• Naturwissenschaften Chemie Organische Chemie Polymerchemie
• Technische Wissenschaften Maschinenbau | Werkstoffkunde Technische Mechanik | Werkstoffkunde Materialwissenschaft: Polymerwerkstoffe
• Technische Wissenschaften Verfahrenstechnik | Chemieingenieurwesen | Biotechnologie Technologie der Kunststoffe und Polymere

Inhaltsverzeichnis

Foreword by Sir Richard Friend xv

Preface xvi

Part 1: Multiphase Systems: Synthesis, Properties and Applications

1 Conjugated Polymer-based Blends, Copolymers, and Composites: Synthesis, Properties, and Applications 3
Parveen Saini

1.1 Introduction 4

1.2 CPs/ICPs-Based Blends 7

1.2.1 Classification of CPs/ICPs-Based Blends 8

1.3 CPs/ICPs-Based Copolymers (CCPs) 11

1.3.1 Types of CPs/ICPs-Based Copolymers 11

1.3.2 Sub-Classification of Linear or Graft BCPs 20

1.4 CPs/ICPs-Based Composites/Nanocomposites/Hybrids 23

1.4.1 Categorization of CPs/ICPs-Based NCs 26

1.5 Interpenetrating/Semi-Interpenetrating Polymer Network (IPN/SIPN) 29

1.6 Synthesis of CPs/ICPs-Based BLNs, CCPs, and CMPs/NCs/HYBs 30

1.6.1 Synthesis of Undoped CPs-Based BLNs 30

1.6.2 Synthesis of Conjugated Polymers-Based Copolymers 39

1.6.3 CPs/ICPs-Based CMPs/NCs 52

1.7 Applications of CPs/ICPs-Based BLNs, CCPs, and CMPs/NCS/HYBs 63

1.7.1 ICP-Based Systems 63

1.7.2 CPs-Based Systems 63

1.8 Conclusions 79

Acknowledgments 80

References 80

2 Progress in Polyaniline Composites with Transition Metal Oxides 119
Gordana Ciric-Marjanovic

2.1 Introduction 119

2.2 PANI/Transition Metal Oxide Composites 120

2.2.1 PANI Composites with Oxides of the Copper Group of Transition Metals 121

2.2.2 PANI Composites with Oxides of the Zinc Group of Transition Metals 121

2.2.3 PANI Composites with Oxides of the Scandium Group of Transition Metals 124

2.2.4 PANI Composites with Oxides of the Titanium Group of Transition Metals 126

2.2.5 PANI Composites with Oxides of the Vanadium Group of Transition Metals 131

2.2.6 PANI Composites with Oxides of the Chromium Group of Transition Metals 132

2.2.7 PANI Composites with Oxides of the Manganese Group of Transition Metals 137

2.2.8 PANI Composites with Oxides of Iron, Cobalt, and Nickel Groups of Transition Metals 140

2.3 Conclusions and Outlook 151

Abbreviations 152

References 153

3 Conjugated-Polymer/Quantum-Confined Nanomaterials-Based Hybrids for Optoelectronic Applications 163
Anuushka Pal, Parveen Saini, and Sameer Sapra

3.1 Introduction 164

3.2 Quantum-Confined Nanomaterials (QCNs) 165

3.2.1 Inorganic Quantum-Confined Nanomaterials (QCNs) 166

3.2.2 Organic Quantum-Confined Nanomaterials (QCNs) 167

3.3 Synthetic Approaches for Quantum-Confined Nanomaterials (QCNs) 168

3.3.1 Synthesis of Inorganic Quantum-Confined Nanomaterials 169

3.3.2 Synthesis of Organic Quantum-Confined Nanomaterials 174

3.3.3 Optical Properties 176

3.4 Conjugated-Polymer/Quantum-Confined Nanomaterials (CP/QCN) Hybrids 183

3.4.1 Methodologies for Making Conjugated-Polymer/Inorganic QCN Hybrids 183

3.4.2 Chemical Methods 184

3.5 Optoelectronic Applications of Hybrids 190

3.5.1 Hybrid Solar Cell 190

3.5.2 Light-Emitting Diodes 201

3.5.3 GQDs/Conjugated-Polymer-Based Counter Electrode for Dye-Sensitized Solar Cells 208

3.6 Outlook and Perspective: Current Challenges and Future Scope/Prospects 210

Acknowledgments 211

References 211

4 Graphene/Conjugated Polymer Nanocomposites for Optoelectronic and Biological Applications 229
Tapas Kuila, Yu Dong Sheng, and Naresh Chandra Murmu

4.1 Introduction 230

4.2 Graphene/Conjugated Polymer Nanocomposites 231

4.2.1 Preparation of Graphene/Conjugated Polymer Nanocomposites 232

4.2.2 Different Types of Conjugated Polymer Nanocomposites and Their Properties 234

4.2.3 Characterizations of Graphene/Conjugated Polymer Nanocomposites 252

4.3 Applications of Graphene/Conjugated Polymer Nanocomposites 263

4.3.1 Optoelectronic Application 263

4.3.2 Biological Applications 268

4.4 Conclusions and Future Scope 270

Über Autor(innen)

Parveen Saini has been a scientist at the National Physical Laboratory, New Delhi, India since 2004. He obtained his PhD in Polymers and Engineering from the Indian Institute of Technology, New Delhi, India, and thereafter, he worked as an engineer at the Sriram Institute for Industrial Research, New Delhi. His research interests include conducting polymers, carbon nanotubes, graphene, conducting polymer nanocomposites for electromagnetic interference (EMI) shielding, microwave absorption, antistatic/electrostatic dissipation (ESD), anticorrosive, and battery applications. He has authored more than 50 scientific publications, book chapters, and patents. He is the recipient of the prestigious CSIR Young Scientist Award-2013 in the area of Engineering Science.