Stuart XXIVth International Congress of Pure and Applied Chemistry

Plenary and Main Section Lectures Presented at Hamburg, Federal Republic of Germany, 2-8 September 1973
1. Auflage 2013
ISBN: 978-1-4832-8015-8
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 156 Seiten, Web PDF

XXIVth International Congress of Pure and Applied Chemistry, Volume 4 contains lectures presented at the XXIVth International Congress of Pure and Applied Chemistry held at Hamburg, Federal Republic of Germany in September 1973. The book consists of papers discussing a wide range of subjects on pure and applied chemistry. The compendium has papers that deal with developments in the chemistry of the boron and silicon subhalides, chemical properties of the Si-H bond, and reactivity of phosphorus heterocycles. The text also presents papers covering topics on the effects of sulfur groups on acidities of carbon acids, aspects of the structural chemistry of polythionates, and Halogen cations. The book will be of use to chemists.

Dr. Sam Stuart is a physiotherapist and a research Fellow within the Balance Disorders Laboratory, OHSU. His work focuses on vision, cognition and gait in neurological disorders, examining how technology-based interventions influence these factors. He has published extensively in world leading clinical and engineering journals focusing on a broad range of activities such as real-world data analytics, algorithm development for wearable technology and provided expert opinion on technology for concussion assessment for robust player management. He is currently a guest editor for special issues (sports medicine and transcranial direct current stimulation for motor rehabilitation) within Physiological Measurement and Journal of NeuroEngineering and Rehabilitation, respectively.

Autoren/Hrsg.

Stuart, Sam

Inhaltsverzeichnis

1;Front Cover;1
2;XXIVth International Congress of Pure and Applied Chemistry;4
3;Copyright Page;5
4;Table of Contents;6
5;CHAPTER 1. NON-METAL CHEMISTRY AT A CROSSROADS? A CASE HISTORY;8
5.1;ABSTRACT;8
5.2;INTRODUCTION;8
5.3;INSERTION REACTIONS IN PEROXIDES;10
5.4;OTHER STUDIES OF PROMISE;17
5.5;CONCLUSION;17
5.6;ACKNOWLEDGMENT;17
5.7;REFERENCES;18
6;CHAPTER 2. NEUERE ERGEBNISSE UND ASPEKTE DER BORCHEMIE;20
6.1;ABSTRACT;20
6.2;SUBSTITUENTENAUSTAUSCH UND BORYLGRUPPENVERSCHIEBUNG;21
6.3;STABILITATSPROBLEME CYCLISCHER BORVERBINDUNGEN;24
6.4;LIGANDENFUNKTION VON BORAN-DERIVATEN;28
7;CHAPTER 3. DEVELOPMENTS IN THE CHEMISTRY OF THE BORON AND SILICON SUBHALIDES;32
7.1;ABSTRACT;32
7.2;INTRODUCTION;32
7.3;EXPERIMENTAL METHODS;32
7.4;SOME BORON-FLUORINE CHEMISTRY;33
7.5;REACTIONS OF BORON MONOCHLORIDE;35
7.6;ADDITION AND INSERTION REACTIONS OF SiCl2;36
7.7;CONCLUSIONS;37
7.8;REFERENCES;37
8;CHAPTER 4. CHEMICAL PROPERTIES OF THE Si-H BOND;38
8.1;ABSTRACT;38
8.2;TRICHLOROSILANE (SiHCl3 );38
8.3;References;51
9;CHAPTER 5. ADVANCES IN THE CHEMISTRY OF BIOLOGICALLY ACTIVE ORGANOSILICON COMPOUNDS;52
9.1;ABSTRACT;52
9.2;REFERENCES;71
10;CHAPTER 6. THE HYDROLYSIS OF PHOSPHATE ESTERS AND RELATED COMPOUNDS: MONOMERIC METAPHOSPHATES AND PHOSPHORIMIDATES;74
10.1;ABSTRACT;74
10.2;INTRODUCTION;74
10.3;MONOMERIC METAPHOSPHATES;75
10.4;MONOMERIC METHYL METAPHOSPHATE;77
10.5;MONOMERIC METAPHOSPHORIMIDATES;80
10.6;MONOMERIC METAPHOSPHORIMIDATES BY PHOTOLYSIS;81
10.7;ACKNOWLEDGMENTS;86
10.8;REFERENCES;86
11;CHAPTER 7. REACTIVITY OF PHOSPHORUS HETEROCYCLES;88
11.1;ABSTRACT;88
11.2;INTRODUCTION;88
11.3;TERVALENT PHOSPHORUS COMPOUNDS;91
11.4;GENERAL SUMMARY;99
11.5;REFERENCES;101
12;CHAPTER 8. EFFECTS OF SULFUR GROUPS ON ACIDITIES OF CARBON ACIDS;104
12.1;ABSTRACT;104
12.2;ACIDITIES OF PARENT CARBON ACIDS;104
12.3;EFFECT OF PHENYL SUBSTITUTION;105
12.4;EFFECT OF PHENYLTHIO SUBSTITUTION;106
12.5;MISCELLANEOUS SUBSTITUENT EFFECTS;107
12.6;REFERENCES;108
13;CHAPTER 9. ASPECTS OF THE STRUCTURAL CHEMISTRY OF POLYTHIONATES;110
13.1;ABSTRACT;110
13.2;INTRODUCTION;110
13.3;STRUCTURES OF TETRA-, PENTA-, AND HEXATHIONATES;111
13.4;METHYLXANTHATES OF DIVALENT SULPHUR, SELENIUM, AND TELLURIUM;115
13.5;THE PREVALENCE OF UNBRANCHED SULPHUR CHAINS;118
13.6;REFERENCES;118
14;CHAPTER 10. HALOGEN FLUORIDES;122
14.1;ABSTRACT;122
14.2;INTRODUCTION;122
14.3;HALOGEN FLUORIDE MOLECULES;122
14.4;HALOGEN FLUORIDE IONS;130
14.5;STRUCTURAL RELATIONS AND BONDING;132
14.6;HALOGEN FLUORIDE RADICALS;140
14.7;APPLICATION IN CHEMICAL LASERS;141
14.8;CONCLUSIONS AND OUTLOOK;141
14.9;ACKNOWLEDGEMENT;141
14.10;REFERENCES;142
15;CHAPTER 11. HALOGEN CATIONS;150
15.1;ABSTRACT;150
15.2;INTRODUCTION;150
15.3;DIATOMIC CATIONS;151
15.4;FLUOROCATIONS;155
15.5;REFERENCES;156