E-Book, Englisch, 543 Seiten
Sunandana Introduction to Solid State Ionics
Erscheinungsjahr 2015
ISBN: 978-1-4822-2971-4
Verlag: Taylor & Francis
Format: PDF
Kopierschutz: Adobe DRM (»Systemvoraussetzungen)
Phenomenology and Applications
E-Book, Englisch, 543 Seiten
ISBN: 978-1-4822-2971-4
Verlag: Taylor & Francis
Format: PDF
Kopierschutz: Adobe DRM (»Systemvoraussetzungen)
From fundamental concepts such as the nature of the superionic bond and its fluctuations, to phonons and electronic structure, this book offers comprehensive insight into the nature of the superionic solid state essentially attained through structural phase transitions with useable materials design synthesis and characterization technologies including nanoionics. An ideal reference for contemporary electrochemical energy conversion applications, the text combines principles and practice to provide a holistic treatment of ionic materials, presenting a healthy balance of phenomenology, theory, and applications while maintaining depth and focus.
Autoren/Hrsg.
Fachgebiete
Weitere Infos & Material
Prologue
Introduction
Perspectives
The (Un)Common Salt
Nature’s Brain Power Source
Electrolyte Balance in Human Body
Mineralogy and History
The Ionic Solid State: Home of Defects and Disorder
Metals, Semiconductors Insulators, and Fast Ion Conductors
Defects in Ionic Crystals: Schottky and Frenkel
Open Structures, Stuffed Structures, and Sublattices
Einstein Solids, (Non-)Debye Solids
Brillouin Zones, Jones Zones
Electronic Structure
Physics of Ionic Conduction
Ion Diffusion vis a vis Electron Diffusion
Conductivity Basics: Ionic, Electronic, and Mixed Conductivity
Structure-Defect-Ion Dynamics Nexus
Scope of the Book
References
Solid State Ionic Materials
Phase Diagrams and Phase Stability of Ionic Materials
Classification of Solid State Ionic Materials
The Lithium Family
The Sodium Family
The Oxygen Family
The Fluorine Family
Phase Transition as a Paradigm of Solid State Ionics
Summary
References
Materials Synthesis
Bulk Solid State Ionic Materials
High Temperature Solid State Synthesis
Temperature-Controlled Precipitation Synthesis
Sol-Gel: Combustion or Solvothermal Synthesis
Mechano-Chemical Reaction Synthesis
Hydrothermal Synthesis
Microwave Synthesis
Thin Film Synthesis Technologies
Physical Vapor Deposition
Resistive Thermal Evaporation
E-Beam Evaporation
RF Magnetron Sputtering
Chemical Vapour Deposition
Ion Beam Evaporation of Single and Multilayers
Fabrication of the Li-Ion Battery
Coin Battery
Thin Film Battery
Summary
References
Characterization
Materials
Crystal Structure
X-Ray Diffraction
Neutron Diffraction
Electron Microscopy and Diffraction
Diffusion
Conductivity
Thermal Characterization
Heat Capacity and Thermal Expansion
Thermoelectric Coefficients
Thermal Conductivity
Spectroscopic Characterization
Electrical Impedance and Dielectric Spectroscopy
UV Visible Optical and Photoacoustic Spectroscopy
Vibrational Spectroscopy: IR and Raman
NMR EPR and Mossbauer Spectroscopy
Devices
Electrochemical Characterization of the Li-Ion Battery
Capacitor Characteristics
Characterization of Solid Oxide Fuel Cells and Gas Sensors
Summary
References
Phase Transitions in Solid State Ionic Materials
Introduction
Models and Theories
O’Reilley Theory of First Order Phase Transitions
Mezrin’s Approach to the Faraday Transition
Coulomb-Driven Transition in Fluorites
Random Variable Theory of Phase Transition in AgI
Other Models
Athermal Phase Transitions
Order-Disorder Phase Transitions in Li-Transition Metal Oxides
Summary
References
Phonons
The Interatomic Potential
Phonon Dispersion in Typical Solid State Ionic Materials
Anharmonicity and Its Consequences
Optical Phonons in AgI-Type Compounds
Raman Phonons in Ag-beta Alumina
The Kramers Problem
Soft Modes
Summary
References
Electronic Structure
Nature of the Superionic Bond
Bond Fluctuations and Phase Transitions
Critical Ionicity, Marginal Covalency, and Electronic Structure
Density Functional Theory of Electronic Structure of Superionic Conductors
Electron Relaxation in LiFePO4
Role of Electronic Structure in the Ion Dynamics of 2D and 3D Li Compounds
Summary
References
The All-Solid-State Battery
Nature's Own Battery and the Car Battery
Battery Basics: Kittel and Kroemer
The Li+ Ion Physics and Battery Components
The Cathode
The Electrolyte
The Anode
The Lithium-Air /Lithium-Oxygen Battery
The Prototype
Thin Film Battery
The Na+ Ion Battery
Polymer Battery
Highly Flexible Printed Batteries
Advanced Lithium Ion Battery Technologies
Systems Architecture and Integration
The Electric Vehicle Challenge
Hybrid Battery Devices
Special Applications: Space, Medical, Emergency, and Backup
Summary
References
Fuel Cells
Fuel Chemical Energy Converts to Electrical Power
Basics of Energy Conversion Process
Fuel Cell Elements
Physics of the Solid Oxide
Design and Evaluation of Solid Oxide Fuel Cell
SOFC vis a vis MCFC and Other Types
Outlook
References
Nanoionics
The Ionic Nanosolid vis a vis the Bulk Solid
Structure Defects and Conductivity
Thermodynamics and Electrostatics
Phase Transitions in Nanoionics
Physics for Devices
Superionic Superlattices
Supercapacitors
Novel Materials Strategies
Thin Film Devices
Projections for the Future
Summary
References
Epilogue
Problems
Index
