Suschitzky / Aaa Progress in Heterocyclic Chemistry

A Critical Review of the 1992 Literature Preceded by Two Chapters on Current Heterocyclic Topics
1. Auflage 2013
ISBN: 978-1-4832-8782-9
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, Band Volume 5, 350 Seiten, Web PDF

Reihe: Progress in Heterocyclic Chemistry

Progress in Heterocyclic Chemistry Volume 5 deals critically with original material selected essentially from the 1992 heterocyclic literature. Chapters 1 and 2 are given over to reviews: in the first, SO2 extrusion from five-membered rings is discussed by R.A. Aitken and colleagues, which completes last year's review on this topic. The second review presents a review of 2-acylamino-3-dimethylaminopropenoates in heterocyclic synthesis. The chapters are arranged according to ring sizes as in the previous volumes and are supported by references, numerous diagrams and a subject index.

Autoren/Hrsg.

Suschitzky, H.

Aaa, E. F. V.

Inhaltsverzeichnis

1;Front Cover;1
2;Progress in Heterocyclic Chemistry;4
3;Copyright Page;5
4;Table of Contents;6
5;Foreword;8
6;Advisory Editorial Board Members;9
7;Chapter 1. Extrusion of S02 from Heterocyclic Compounds, Part 2: Five-Membered Rings;10
7.1;1.1 SULPHOLANES;10
7.2;1.2 SULPHOLENES;15
7.3;1.3 THIOPHENE DIOXIDES;25
7.4;1.4 RINGS CONTAINING ONLY O AND S;28
7.5;1.5 RINGS CONTAINING ONLY N AND S;33
7.6;1.6 RINGS CONTAINING O AND N;37
7.7;1.7 REFERENCES;38
8;Chapter 2. Methyl 2-Benzoylamino-3- dimethylaminopropenoate in the Synthesis of Heterocyclic Systems;43
8.1;2.1 Introduction;43
8.2;2.2 The synthesis of ß-heteroaryl-a, ß-dehydro-a-amino acid derivatives (Methy1 2-benzoylamino-3-heteroarylpropenoates);47
8.3;2.3 The synthesis of methy1 substituted 3-amino-2-benzoylaminopropenoates;47
8.4;2.4 The Synthesis of pyranones and fused pyranones;48
8.5;2,5 The synthesis of pyranopyranones and benzopyranopyranones;53
8.6;2.6 The synthesis of pyrano[2,3-c] pyrazoles;53
8.7;2.7 The synthesis of pyranopyridines, pyranoguinolines and other condensed pyranoazines;54
8.8;2,8 The synthesis of bicyclic systems with a bridgehead nitrogen atom;56
8.9;2.9. References;60
9;Chapter 3. Three-Membered Ring Systems;63
9.1;3.1 INTRODUCTION;63
9.2;3.2 EPOXIDES;63
9.3;3.3 DIOXIRANES;72
9.4;3.4 OXAZIRIDINES;73
9.5;3.5 AZIRIDINES;74
9.6;3.6 References;76
10;Chapter 4. Four-Membered Ring Systems;78
10.1;4.1 INTRODUCTION;78
10.2;4.2 AZETES AND AZETIDINES;78
10.3;4.3 OXETANES AND THIETANES;79
10.4;4.4 DIOXETANES, DIAZETE AND DITHIETANE;81
10.5;4.5 OXATHIETANES AND THIAZETIDINES;81
10.6;4.6 BORON, SILICON AND PHOSPHORUS HETEROCYCLES;82
10.7;4.7 AZETIDINONES;83
10.8;REFERENCES;87
11;Chapter 5.1 Five-Membered Ring Systems: Thiophenes & Se & Te Analogs;91
11.1;5.1.1 INTRODUCTION;91
11.2;5.1.2 AROMATICITY AND ELECTRONIC CHARACTER;91
11.3;5.1.3 RING SUBSTITUTION;94
11.4;5.1.4 THIOPHENE RING FORMATION;99
11.5;5.1.5 RING ANNELATION ON THIOPHENE;103
11.6;5.1.6 THIOPHENES AS INTERMEDIATES;105
11.7;5.1.7 POLYMERS AND MACROMOLECULES;107
11.8;5.1.8 SELENOPHENES AND TELLUROPHENES;109
11.9;5.1.9 INTERESTING THIOPHENE DERIVATIVES;110
11.10;5.1.10 REFERENCES;110
12;Chapter 5.2 Five-Membered Ring Systems: Pyrroles and Benzo Derivatives;119
12.1;5.2.1 Methods for Ring Synthesis;119
12.2;5.2.2 Ring Substitution and Modification Reactions;125
12.3;5.2.3 Annulation Reactions;129
12.4;References;135
13;Chapter 5.3 Five-Membered Ring Systems: Furans and Benzo Derivatives;138
13.1;5.31 INTRODUCTION;138
13.2;5.3 2 REACTIONS;139
13.3;5.33 RING SYNTHESIS;142
13.4;REFERENCES;149
14;Chapter 5.4 Five-Membered Ring Systems: With More than One N Atom;152
14.1;5.4.1 INTRODUCTION;152
14.2;5.4.2 PYRAZOLES AND FUSED-RING PYRAZOLES;152
14.3;5.4.3 IMIDAZOLES AND FUSED-RING IMIDAZOLES;155
14.4;5.4.4 1,2,3-TRIAZOLES AND FUSED-RING DERIVATIVES;158
14.5;5.4.5 1,2,4-TRIAZOLES AND FUSED-RING DERIVATIVES;160
14.6;5.4.6 TETRAZOLES AND FUSED-RING DERIVATIVES;162
14.7;5.4.7 REFERENCES;163
15;Chapter 5.5 Five-Membered Ring Systems: With N & S (Se) Atoms;168
15.1;5-5.1 Thiazoles;168
15.2;5.5.2 Isothiazoles;172
15.3;5.5.3 Thiadiazoles;174
15.4;REFERENCES;179
16;Chapter 5.6 Five-Membered Ring Systems: With O & S (Se, Te) Atoms;182
16.1;5.6.1 1,3-Dioxoles and Dioxolanes;182
16.2;5.6.2 1,3-Dithioles and Dithiolanes;184
16.3;5.6.3 1,3-Oxathioles and Oxathiolanes;187
16.4;5.6.4 1,2-DioxoIes and Dioxolanes;188
16.5;5.6.5 1,2-Dithioles and Dithiolanes;189
16.6;5.6.6 1,2-Oxathiolanes;190
16.7;5.6.7 Three Heteroatoms;190
16.8;5.6.8 References;190
17;Chapter 5.7 Five-Membered Ring Systems: With O & N Atoms;194
17.1;5.7.1 ISOXAZOLES;194
17.2;5.7·2 ISOXAZOLINES;196
17.3;5.7.3 ISOXAZOLIDINES;199
17.4;5.7.4 OXAZOLES AND BENZOXAZOLES;199
17.5;5·7.5 OXAZOLINES;202
17.6;5.7·6 OXAZOLIDINES AND OXAZOLIDINONES;204
17.7;5.7.7 OXADIAZOLES;207
17.8;5.7.8 REFERENCES;208
18;Chapter 6.1 Six-Membered Ring Systems: Pyridine and Benzo Derivatives;211
18.1;6.1.1 SYNTHESIS;211
18.2;6.2.1 REACTIONS;220
18.3;REFERENCES;225
19;Chapter 6.2 Six-Membered Ring Systems: Diazines and Benzo Derivatives;229
19.1;6.2.1 SYNTHESIS;229
19.2;6.2.2 REACTIONS;235
19.3;REFERENCES;245
20;Chapter 6.3 Six-Membered Ring Systems: Triazines, Tetrazines and Fused Ring Polyaza Systems;248
20.1;63.1 SYNTHESIS;248
20.2;63.2 REACTIONS;263
20.3;REFERENCES;270
21;Chapter 6.4 Six-Membered Ring Systems: With O and/or S Atoms;273
21.1;Introduction;273
21.2;6.4.1 HETEROCYCLES CONTAINING ONE OXYGEN ATOM;273
21.3;6.4.2 HETEROCYCLES CONTAINING ONE SULFUR ATOM;287
21.4;6.4.3 HETEROCYCLES CONTAINING TWO OR MORE OXYGEN ATOMS;290
21.5;6.4.4 HETEROCYCLES CONTAINING TWO OR MORE SULFUR ATOMS;293
21.6;6.4.5 HETEROCYCLES CONTAINING BOTH OXYGEN AND SULFUR IN THE SAME RING;294
21.7;6.4.6. REFERENCES;294
22;Chapter 7. Seven-Membered Rings;299
22.1;INTRODUCTION;299
22.2;7.1 7-Membered Rings with Nitrogen;300
22.3;7.2 7-Membered Rings with Oxygen;310
22.4;7.3 7-Membered Rings with Sulfur;314
22.5;7.4 7-Membered Rings with Heteroatom Combinations;316
22.6;REFERENCES;322
23;Chapter 8. Eight-Membered and Larger Rings;331
23.1;8.1 INTRODUCTION;331
23.2;8.2 CARBON-OXYGEN RINGS;332
23.3;8.3 CARBON-NITROGEN RINGS;333
23.4;8.4 CARBON-SULFUR RINGS;336
23.5;8.5 CARBON-PHOSPHORUS RINGS;338
23.6;8.6 CARBON-OXYGEN-NITROGEN RINGS;338
23.7;8.7 CARBON-OXYGEN-SULFUR RINGS;339
23.8;8.8 CARBON-NITROGEN-SULFUR RINGS;340
23.9;8.9 CARBON-SULFUR-PHOSPHORUS;341
23.10;8.10 CARBON-OXYGEN-TELLURIUM;341
23.11;8.11 REFERENCES;342
24;SUBJECT INDEX;348