Marciniec Comprehensive Handbook on Hydrosilylation

1. Auflage 2013
ISBN: 978-0-08-091243-1
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 776 Seiten, Web PDF

This handbook provides an up-to-date account of hydrosilylation reactions and the directions in which synthetic and mechanistic studies as well as practical applications of these processes are proceeding. The book consists of two parts: the first is descriptive, presenting the catalytic, mechanistic, structural and synthetic aspects of hydrosilylation, as well as its application in organic and organosilicon chemistry. The second part, presented in tabular form sets out encyclopedic information concerning reaction conditions taken from more than 2000 papers and patents in the period 1965 - 1990.

Autoren/Hrsg.

Marciniec, B.

Inhaltsverzeichnis

1;Front Cover;1
2;Comprehensive Handbook on Hydrosilylation;4
3;Copyright Page;5
4;Table of Contents;10
5;Preface;8
6;Part I: General Survey;14
6.1;Chapter 1. Introduction;16
6.2;Chapter 2. Catalytic Aspects of Hydrosilylation;21
6.2.1;2.1 Free-radical Addition;21
6.2.2;2.2 Nucleophilic–Electrophilic Catalysis;35
6.2.3;2.3 Metal Catalysts;42
6.2.4;2.4 Homogeneous Catalysis by Transition Metal Complexes;45
6.2.5;2.5 Catalysis by Supported Transition Metal Complexes;97
6.2.6;2.6 Photo- and Peroxide-initiated Catalysis by Metal Complexes;107
6.3;Chapter 3. The Reactivity in Hydrosilylation of Particular Types of Organic Compounds with Multiple Bonds;112
6.3.1;3.1 Hydrocarbons with an Isolated C = C Bond;112
6.3.2;3.2 Hydrocarbons with Two or More C = C Bond;120
6.3.3;3.3 Alkene and Cycloalkene Derivatives with Functional Groups;129
6.3.4;3.4 Hydrocarbons with an Isolated C = C Bond;143
6.3.5;3.5 Alkyne Derivatives with Functional Groups;147
6.3.6;3.6 Hydrocarbons Containing C =C and C =C Bonds and Their Derivatives;151
6.3.7;3.7 Saturated Carbonyl Compounds;152
6.3.8;3.8 Unsaturated Carbonyl Compounds;158
6.3.9;3.9 Compounds with Carbon–Nitrogen Multiple Bonds;168
6.3.10;3.10 Compounds with Other Multiple Bonds;171
6.4;Chapter 4. The Effect of Substituents at Silicon on the Reactivityof the Si–H Bond in Hydrosilylation;173
6.4.1;4.1 Effect of the Structure of Silicon Hydrides on the Rate and Yield inHydrosilylation Processes;173
6.4.2;4.2 Influence of the Structure of the Silicon Hydride on Regio- and Stereoselectivity in Hydrosilylation;183
6.4.3;4.3 Practical Choice of Silicon Hydride in the Hydrosilylation Reaction;189
6.5;Chapter 5. The Hydrosilylation of Unsaturated Organosilicon Compounds;191
6.5.1;5.1 Addition of Substituted Hydrosilanes to Carbon–Carbon Double Bonds in Unsaturated Silanes;191
6.5.2;5.2 Addition of Substituted Hydrosilanes and Hydrosiloxanes to Unsaturated Silanes and Siloxanes to Yield Carbosiloxane Derivatives;197
6.5.3;5.3 Curing Organosilicon Polymers by Hydrosilylation;201
6.5.4;5.4 Addition of Substituted Hydrosilanes to Carbon–Carbon Triple Bondsin Unsaturated Silanes;205
6.5.5;5.5 Poly addition of Di-, Tri- and Tetra-functional Silicon Hydride Derivatives to Di-, Tri- and Tetra-functional Unsaturated Organosilicon Monomers;209
6.5.6;5.6 Intra- and Intermolecular Hydrosilylation;213
6.6;Chapter 6. The Application of Hydrosilylation Processes;217
6.6.1;6.1 Silanes as Coupling Agents;217
6.6.2;6.2 Reduction of Organic Compounds by Hydrosilylation;223
6.6.3;6.3 Modification of Polymers via Hydrosilylation;228
7;Part II: A Compilation of Information on Hydrosilylation Studies over the Period from 1965 to 1990;232
7.1;List of Tables;236
7.2;Abbreviations;239
7.3;Tables/ Figures;242
8;Bibliography;708
8.1;Reviews;708
8.2;Papers;709
8.3;Patents;748
9;Index;764