Tomlinson / Robinson An Introduction to the Chemistry of Benzenoid Compounds

1. Auflage 2016
ISBN: 978-1-4832-8024-0
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 218 Seiten, Web PDF

An Introduction to the Chemistry of Benzenoid Compounds is an introductory text to some chemical aspects of benzenoid compounds. This book is composed of 13 chapters that specifically cover the sources, properties, and reactions of these compounds. The opening chapters describe the structural aspects of benzenoid compounds, including their homologues, isomers, and aromaticity. The subsequent chapters deal with the disubstitution and addition reactions of the benzene nucleus. Considerable chapters are devoted to the synthesis of benzenoid derivatives, such as aromatic halides, nitro-compounds, carbonyl compounds, acids, and amines, phenols, alcohols, and naphthalene. The final chapter introduces the chemistry of anthracene, phenanthrene, and polycyclic aromatic hydrocarbons. This book is of value to organic chemistry students.

Autoren/Hrsg.

Tomlinson, Muriel

Robinson, Robert

Inhaltsverzeichnis

1;Front Cover;1
2;An Introduction to the Chemistry of Benzenoid Compounds;4
3;Copyright Page;5
4;Dedication;6
5;Table of Contents;8
6;Publisher's Note;9
7;Preface;10
8;Editor's Preface;11
9;CHAPTER 1. The Structure of Benzene;12
9.1;FURTHER READING;22
10;CHAPTER 2. Benzene and Its Homologues:the Substitution Reactions of Benzene;23
10.1;SOURCES AND PREPARATIONS;23
10.2;THE SUBSTITUTION REACTIONS OF THE BENZENE NUCLEUS. THE EXPERIMENTAL FINDINGS;25
10.3;FURTHER READING;38
11;CHAPTER 3. Disubstitution in Benzenoid Compounds;39
11.1;SEPARATION OF ISOMERS;39
11.2;DETERMINATION OF ORIENTATION;40
11.3;FURTHER SUBSTITUTION INTO SUBSTITUTEDBENZENOID COMPOUND;42
11.4;PARTIAL RATE FACTORS;43
11.5;ELECTRONIC EFFECTS OF SUBSTITUENTS ON THE BENZENE NUCLEUS;44
11.6;DIPOLE MOMENTS OF ARYL-X COMPARED WITH ALKYL-X;47
11.7;FURTHER CONSIDERATION OF THE MECHANISM OF AROMATIC SUBSTITUTION;48
11.8;NUCLEOPHILIC SUBSTITUTION IN BENZENOID COMPOUNDS;56
11.9;COMPARISON OF ADDITION TO ETHYLENES WITH SUBSTITUTION INTO BENZENES;57
11.10;SUBSTITUTION BY RADICALS INTO BENZENOID COMPOUNDS;61
11.11;FURTHER READING;62
12;CHAPTER 4. The Addition Reactions of the Benzene Nucleus;64
12.1;FURTHER READING;70
13;CHAPTER 5. Aromaticity;71
13.1;FURTHER READING;80
14;CHAPTER 6. Aromatic Halides;81
14.1;NUCLEAR HALIDES;81
14.2;SIDE-CHAIN AROMATIC HALIDES;87
14.3;NOTE ADDED IN PROOF;91
14.4;FURTHER READING;91
15;CHAPTER 7. Aromatic Nitro-compounds;92
15.1;REDUCTION OF NITRO-COMPOUNDS;94
15.2;FURTHER READING;100
16;CHAPTER 8. Aromatic Amines;101
16.1;PREPARATION;101
16.2;PROPERTIES AND REACTIONS;103
16.3;NUCLEAR SUBSTITUTIONS;105
16.4;OXIDATION;106
16.5;ACYLATION;108
16.6;DIAZOTISATION AND DIAZONIUM SALTS;111
16.7;REACTIONS OF DIAZONIUM SALTS;113
16.8;FURTHER READING;123
17;CHAPTER 9. Phenols and Alcohols;124
17.1;PHENOLS;124
17.2;DIHYDRIC PHENOLS;139
17.3;AMINOPHENOLS;143
17.4;TRIHYDRIC PHENOLS;143
17.5;AROMATIC ALCOHOLS;145
17.6;FURTHER READING;149
18;CHAPTER 10. Aromatic Carbonyl Compounds;150
18.1;PREPARATION;150
18.2;PROPERTIES;154
18.3;OXIDATION AND REDUCTION;154
18.4;REACTIONS OF THE NUCLEUS;156
18.5;REACTIONS OF THE CARBONYL: GROUP;156
18.6;BASE-CATALYSED REACTIONS WITH AROMATIC ALDEHYDES;161
18.7;PHENACYL HALIDES;163
18.8;OXIMES;164
18.9;FURTHER READING;166
19;CHAPTER 11. Aromatic Acids;167
19.1;CARBOXYLIC ACIDS;167
19.2;ACID CHLORIDES;170
19.3;HYDROXYBENZOIC ACIDS;171
19.4;AMINOBENZOIC ACIDS;172
19.5;PHTHALIC ACIDS;173
19.6;SIDE-CHAIN ACIDS;176
19.7;SULPHONIC ACIDS;178
19.8;FURTHER READING;181
20;CHAPTER 12. Naphthalene;182
20.1;THE STRUCTURE OF NAPHTHALENE;182
20.2;SYNTHESES;184
20.3;NUMBERING AND ORIENTATION;185
20.4;REACTIONS OF NAPHTHALENES;186
20.5;NAPHTHALENE DERIVATIVES;191
20.6;DECALOLS, DECALONES, AND DECALINS;195
20.7;FURTHER READING;196
21;CHAPTER 13. Introduction to the Chemistry of Anthracene,Phenanthrene, and Polycyclic Aromatic Hydrocarbons;197
21.1;SYNTHESES;198
21.2;ANTHRACENE;200
21.3;ELECTROPHILIC SUBSTITUTION OF ANTHRACENE;203
21.4;THE HIGHER LINEAR POLYCYCLIC AROMATIC COMPOUNDS;204
21.5;PHENANTHRENE;207
21.6;ANGULAR POLYCYCLIC COMPOUNDS;209
21.7;FURTHER READING;212
22;Subject Index;214
23;Named Reaction Index;218