Xu Modern Inorganic Synthetic Chemistry

1. Auflage 2010
ISBN: 978-0-444-53600-6
Verlag: Elsevier Science & Techn.
Format: EPUB
Kopierschutz: 6 - ePub Watermark

E-Book, Englisch, 610 Seiten

The book has four main parts. Inÿthe first partÿthe discussion centers on inorganic synthesis reactions, dealing with inorganic synthesis and preparative chemistry under specific conditions: high temperature, low temperature and cryogenic, hydrothermal and solvothermal, high pressure and super-high pressure, photochemical, microwave irradiation and plasma conditions. The second part systematically describes the synthesis, preparation and assembly ofÿsix important categories of compounds with wide coverage of distinct synthetic chemistry systems: coordination compounds, coordination polymers, clusters, organometallic compounds, non-stoichiometric compounds and inorganic polymers. In the third part seven important representative inorganic materials are selected for discussion of their preparation and assembly, including porous, advanced ceramic, amorphous- and nano-materials, inorganic membranes, synthetic crystals and advanced functional materials. The last part of the book, which is also its distinct feature, addresses the frontiers of inorganic synthesis and preparative chemistry. These finalÿtwo chapters introduce the two emerging synthetic areas. Included are approximately 3000 references, a large proportion of which are from the recent decade. - Focuses on the 'chemistry' of inorganic synthesis, preparation and assembly of various compounds and describes all inorganic synthesis methods - New state of the art inorganic synthesis chemistry areas - Inclusion of a number of real examples for the preparation and assembly of important classes of materials - More than 3,000 reference to the primary literature - Comprehensive state of the art reviews written by the experts in the area

Autoren/Hrsg.

Xu, Ruren

Xu, Yan

Inhaltsverzeichnis

1;Front Cover;1
2;Modern Inorganic Synthetic Chemistry;4
3;Copyright;5
4;Contents;6
5;Foreword;16
6;Preface;18
7;Contributors;20
8;Chapter 1 Introduction - Frontiers in Modern InorganicSynthetic Chemistry;22
8.1;1.1Development Of New Synthetic Reactions, Synthetic Routes, Technologies And Associated Basic Scientific Studies;23
8.2;1.2 Basic Research in Support of Green Synthesis;24
8.3;1.3 Basic Research on Synthetic and Preparative Routes Under Extreme Conditions;25
8.4;1.4 Biomimetic Synthesis and Applications of Biotechnology in Inorganic Synthesis;25
8.5;1.5 Rational Synthesis and Molecular Engineering of Inorganic Compounds with Specific Structures and Functions;26
8.6;References;28
9;Chapter 2 High-temperature Synthesis;30
9.1;2.1 Attainment of high temperature-laboratory furnaces [1] and related techniques [2–6];30
9.2;2.2 Types of high-temperature synthetic reactions and routes;32
9.3;2.3 High-temperature solid-state reaction [11–14];32
9.4;2.4 Preparation Of Rare Earthcontaining Materials;35
9.5;2.5 Sol–gel process and precursors in high-temperature solid synthesis [45–47];39
9.6;2.6 Self-Propagating Hightemperature Synthesis (Shs) [51–60];45
9.7;2.7 High-Temperature Preparation Of Metal Vapors And Active Molecules For Use In Cryosynthesis [70–72];48
9.8;2.8 High-temperature electrolysis in molten salt system [73–79];52
9.9;References;58
10;Chapter 3 Synthesis and Purification at Low Temperature;60
10.1;3.1 Attainment And Measurement Of Low And Ultralow Temperatures;60
10.2;3.2 Vacuum Technique and its Application in Inorganic Synthesis;61
10.3;3.3 Purification and Separation of Inorganics at Low Temperature;67
10.4;3.4 The Synthesis of Volatile Inorganic Compounds at Low Temperature;73
10.5;3.5 Formation of Rare-gas Molecules at Cryogenic Condition;74
10.6;3.6 Inorganic Synthesis in Liquid Ammonia;77
10.7;3.7 Cryosynthesis of Unusual Inorganic Compounds [52–55];80
10.8;References;83
11;Chapter 4 Hydrothermal and Solvothermal Syntheses;84
11.1;4.1 Foundation of Hydrothermal and Solvothermal Syntheses [1];84
11.2;4.2 Functional Materials from Hydrothermal and Solvothermal Systems;87
11.3;4.3 Hydrothermal Biochemistry;99
11.4;4.4 Supercritical Water—a Novel Reaction System [106–110];102
11.5;4.5 Techniques and Methods;105
11.6;4.6 Ionothermal Synthesis;110
11.7;References;114
12;Chapter 5 High Pressure Synthesis and Preparationof Inorganic Materials;118
12.1;5.1 Experimental Methods Of Inorganic Synthesis Under High Pressure;119
12.2;5.2 Effects Of High Pressure On Basic States Of Matters;127
12.3;5.3 Effects Of High Pressure On Inorganic Chemical Reactions;131
12.4;5.4 Effects Of High Pressure On Crystal And Electronic Structures Of Inorganic Compounds;132
12.5;5.5 Major Roles Of High Pressure Method In Inorganic Synthesis;138
12.6;5.6 Some Important Inorganic Compounds Synthesized Under High Pressure;141
12.7;References;146
13;Chapter 6 Inorganic Photochemical Synthesis;150
13.1;6.1 The Basic Concepts;150
13.2;6.2 Experimental Techniques;152
13.3;6.3 Photochemical Synthesis Of Organometallic Complexes;153
13.4;6.4 Photochemical Synthesis Of Inorganic Compounds;157
13.5;6.5 Synthesis Of Inorganic Thin Films Via Photochemical Reactions;159
13.6;6.6 Photochemical Synthesis of Nanomaterials;163
13.7;6.7 Production of H2 Via Photodecomposition of Water;164
13.8;6.8 Summary;166
13.9;References;167
14;Chapter 7 CVD and its Related Theories in InorganicSynthesis and Materials Preparations;172
14.1;7.1 Brief History of Chemical Vapor Deposition;172
14.2;7.2 Technical Fundamentals of CVD;173
14.3;7.3 Equipment of Chemical Vapor Deposition;177
14.4;7.4 Some Theoretical Models of CVD Technology;180
14.5;7.5 Thermodynamic Coupling During The Low-Pressure Cvd Diamond Growth;187
14.6;7.6 Nonequilibrium Phase Diagrams For The Low-Pressure Cvd Diamond Growth;188
14.7;References;191
15;Chapter 8 Microwave-assisted Inorganic Syntheses;194
15.1;8.1 Basic Principle Of Microwave Radiation, Microwave Heating, And Microwave Equipment;194
15.2;8.2 Synthesis Of Inorganic Materials Under Microwave Heating;197
15.3;8.3 Synthesis Of Inorganic Materials Assisted With Different Microwave Frequencies;211
15.4;8.4 Plasma-Assisted Synthesis Of Inorganic Materials;211
15.5;8.5 Some Of The Basic Conclusions And Outlooks About Microwave Radiation Associated Chemistry;213
15.6;References;215
16;Chapter 9 Syntheses of Coordination Compounds;218
16.1;9.1 Direct Synthesis Method;218
16.2;9.2 Component Exchange Method [2,3,15];220
16.3;9.3 Redox Interaction Method [3];221
16.4;9.5 Inclusion Complexation Method;224
16.5;References;226
17;Chapter 10 Assembly Chemistry of CoordinationPolymers;228
17.1;10.1 Molecular Design Of Coordination Polymers;230
17.2;10.2 Structural Modulation By Reaction Conditions;235
17.3;10.3 Situ Metal/Ligand Reactions;242
17.4;References;245
18;Chapter 11 Synthetic Chemistry of Cluster Compounds;248
18.1;11.1 Description of the Clusters;248
18.2;11.2 Synthesis Of The Oxo Tm Clusters Under Hydrothermal Conditions;249
18.3;11.2.4 Designed Synthesis Via The Peripheral Substitution Of Ni6pw9 Sbus;255
18.4;11.3 Synthesis Of The Oxo Lanthanide Clusters Under Hydrothermal Conditions;257
18.5;11.3.1 Induced Synthesis Via The Ligands;257
18.6;11.4 Synthesis Of The Oxo Main Group Clusters Under Hydrothermal Conditions;259
18.7;11.5 Synthesis Of The Chalcogenide Clusters Under Hydro(Solvo)Thermal Conditions;264
18.8;References;267
19;Chapter 12 Synthetic Chemistry of Fullerenes;270
19.1;12.1 Synthesis;270
19.2;12.2 Characterization of Fullerenes;273
19.3;12.3 Chemical Reactions;274
19.4;References;284
20;Chapter 13 Synthesis of Organometallic Organometallic Compounds;290
20.1;13.1 Synthetic Reactions;291
20.2;13.2 Preparation of Typical Organometallic Compounds;300
20.3;13.3 Experimental Techniques;310
20.4;References;312
21;Chapter 14 Synthesis and Assembly Chemistryof Inorganic Polymers;316
21.1;14.1 Polyphosphazenes;316
21.2;14.2 Synthesis and Assembly Chemistry of Cyclophosphazene;317
21.3;14.3 Applications of Cyclomatrix Polyphosphazenes;322
21.4;14.4 Silicones;335
21.5;References;339
22;Chapter 15 Synthetic Chemistry of NonstoichiometricCompounds;342
22.1;15.1 Nonstoichiometric Compounds;343
22.2;15.2 Preparation of Nonstoichiometric Compounds;345
22.3;15.3 Characterization Of Nonstoichiometric Compounds;356
22.4;References;358
23;Chapter 16 Synthetic Chemistry of the Inorganic OrderedPorous Materials;360
23.1;16.1 Porous Materials;360
23.2;16.2 Zeolite and its Structure;361
23.3;16.3 The Synthesis of Zeolite;363
23.4;16.4 Zeotype: Zeolite-like Materials;367
23.5;16.5 New Strategies and New Trends of Zeolite Synthesis;369
23.6;16.6 Basic of Ordered Mesoporous Materials;372
23.7;16.7 Understanding the Synthesis of Mesoporous Materials;373
23.8;16.8 Typical Mesostructures and Mesoporous Materials;374
23.9;16.9 Synthesis Strategies for Mesoporous Silica;378
23.10;16.10 Morphology Control in Mesoporous Materials;383
23.11;16.11 New Compositions: Nonsilica-based Mesoporous Materials [13,22];385
23.12;16.12 Porous Carbon Materials;386
23.13;16.13 Ordered Macroporous Materials;389
23.14;16.14 Challenges for Porous Material Scientist;389
23.15;References;390
24;Chapter 17 Assembly Chemistry of Anion-intercalatedLayered Materials;396
24.1;17.1 Structure of Anion-intercalated Layered Materials;396
24.2;17.2 Preparative Chemistry of Anion-intercalated Layered Materials;404
24.3;17.3 Assembly Chemistry of Anion-intercalated Layered Materials;416
24.4;References;419
25;Chapter 18 Host–guest Functional Materials;426
25.1;18.1 Metal Clusters in Zeolites;426
25.2;18.2 Encapsulation of Dyes in Zeolites;431
25.3;18.3 Polymers and Carbon Matters in Zeolites;433
25.4;18.4 Semiconductor Nanoparticles in Zeolites;436
25.5;18.5 Metal Complexes in Molecular Sieves;440
25.6;References;446
26;Chapter 19Chemical Preparation of Advanced CeramicMaterials;450
26.1;19.1 Nanoceramics;450
26.2;19.2Ceramic Matrix Composites(CMCs);456
26.3;19.3 Integration Of Structures And Functions;463
26.4;19.4 Transparent Ceramics;464
26.5;References;471
27;Chapter 20 Amorphous Materials;476
27.1;20.1 Amorphous Structure;476
27.2;20.2 Formation Rule of Amorphous Alloy;482
27.3;20.3 Preparation Technology of Amorphous Materials;489
27.4;20.4 Bulk Amorphous Alloy-based Composite Materials;496
27.5;References;498
28;Chapter 21Synthetic Chemistry of Nanomaterials;500
28.1;21.1 Basics of the Synthetic Chemistry of Nanomaterials;500
28.2;21.2 Synthetic Method for Nanomaterials;501
28.3;21.3 Synthesis of Nanomaterials;511
28.4;21.4 Concluding Remarks;523
28.5;References;523
29;Chapter 22 Preparation Chemistry of Inorganic Membranes;528
29.1;22.1 Inorganic MembranesInorganic Membranes and Their Major Characteristics;528
29.2;22.2 Synthesis of Microporous Inorganic Membranes;529
29.3;22.3 Synthesis of Ordered Mesoporous Membranes;535
29.4;22.4 Conclusions;542
29.5;References;542
30;Chapter 23 The Frontier of Inorganic Synthesis and Preparative Chemistry (I)—Biomimetic Synthesis;546
30.1;23.1 Biomineralization and Its Mimetic Inorganic Materials;546
30.2;23.2 Biotemplated Inorganic Materials;555
30.3;23.3 Biomimetic Synthesis of Inorganic Chiral Materials;560
30.4;23.4 Bio-inspired Multiscale Inorganic Materials;564
30.5;References;570
31;Chapter 24 Frontier of Inorganic Synthesis and PreparativeChemistry (II)-Designed SynthesisdInorganicCrystalline Porous Materials;576
31.1;24.1 Structure Design of Inorganic Crystalline Porous Materials;577
31.2;24.2 Chemical and Physical Problems on Way to the Rational Synthesis of Inorganic Crystalline Porous Materials;590
31.3;24.3 Attempts to the Rational Synthesis of Inorganic Porous Crystalline Materials;591
31.4;24.4 Future Perspective On The Tailor-Made Synthesis Of Desired Inorganic Porous Crystalline Materials;605
31.5;24.5 Concluding Remarks;606
31.6;References;606
32;Subject Index;608