Gielen / Willem / Wrackmeyer Unusual Structures and Physical Properties in Organometallic Chemistry

1. Auflage 2003
ISBN: 978-0-470-85561-4
Verlag: John Wiley & Sons
Format: PDF
Kopierschutz: Adobe DRM (»Systemvoraussetzungen)

E-Book, Englisch, 446 Seiten, E-Book

Reihe: Physical Organometallic Chemistry

The principal idea of this volume is to offer a Capita Selecta ofunconventional and thought-provoking topics in organometallicchemistry, presented by experts in each field. As intended, thisapproach leads either to reviews covering a specific uncommon classof organometallic compounds or to overviews which relate uncommonphysical properties with various classes of organometalliccompounds. The contributions are streamlined thus onto two mainaxes - unusual properties reflecting structures and bondingsituations, on the one hand, and uncommon structural features orstructure-reactivity relationships, on the other. Extensivecross-referencing of useful information is provided, making thisvolume accessible for people working in rather different areas oforganometallic chemistry.
The synthesis of molecules with 'extreme' properties is a challengefor all those working in organometallic chemistry, irrelevant oftheoretical/computational, synthetic or application interests. Thisbook presents case studies at the interface of these overlappinginterests.
Unusual Structures and Physical Properties in OrganometallicChemistry:
* Provides test cases for computational and theoreticalmodels
* Presents a challenge for synthetic chemists
* Provides ideal show cases for analytical techniques
This volume will be an invaluable reference for researchers inorganometallic chemistry, computational and theoretical chemistry,NMR and other spectroscopic methods.

Autoren/Hrsg.

Gielen, Marcel

Willem, Rudolph

Wrackmeyer, Bernd

Inhaltsverzeichnis

Contributors.
Series Preface.
Preface.
1. Structure and Electrochemistry of Transition Metal CarbonylClusters with Interstitial or Semi-Interstitial Atoms: Contrastbetween Nitrides or Phosphides and Carbides (Piero Zanello).
2. Unusual Nuclear Magnetic Shielding and Coupling ConstantsRelated to Unusual Bonding Situations (Bernd Wrackmeyer).
3. Deuterium Spin-Lattice Relaxation and Deuterium QuadrupoleCoupling Constants. A Novel Strategy for Characterization ofTransition Metal Hydrides and Dihydrogen Complexes in Solution(Vladimir I. Bakhmutov).
4. NMR Studies of Ligand Nuclei in Organometallic Compounds--NewInformation from Solid-State NMR Techniques (Guy M. Bernard andRoderick E. Wasylishen).
5. Metal Atom Motion in Some Iron Organometallics (Rolfe H.Herber).
6. Magnetic Communication in Binuclear Organometallic ComplexesMediated by Carbon-Rich Bridges (Frédéric Paul andClaude Lapinte).
7. Molecular Cluster Complexes with Facial Arene Ligands (HerbertWadepohl).
8. Cobaltafulvenes and Cobaltapentalenes: Highly PolarMetallacyclic II-Systems with Unusual Properties (HerbertWadepohl).
9. Novel Highly Nucleophilic Ylidic Ligands for the Preparation ofUnusually Stable Metal Complexes (Norbert Kuhn, Martin Göhner,Gernot Frenking and Yu Chen).
10. Supramolecular Interactions in Structures of Organic Antimonyand Bismuth Compounds (Gabor Balázs and Hans JoachimBreunig).
Index.