Schäfer Chemical Transport Reactions

1. Auflage 1964
ISBN: 978-1-4832-7059-3
Verlag: Elsevier Reference Monographs
Format: PDF
Kopierschutz: Adobe DRM (»Systemvoraussetzungen)

E-Book, Englisch, 174 Seiten

Chemical Transport Reactions focuses on the processes and reactions involved in the transport of solid or liquid substances to form vapor phase reaction products.
The publication first offers information on experimental and theoretical principles and the transport of solid substances and its special applications. Discussions focus on calculation of the transport effect of heterogeneous equilibria for a gas motion between equilibrium spaces; transport effect and the thermodynamic quantities of the transport reaction; separation and purification of substances by means of material transport; and crystalline substances with homogeneous regions. The text then elaborates on the reaction process in the gas phase and chemical transport processes as an aid in preparative chemistry.
The manuscript ponders on the use of transport experiments in the determination of thermodynamic values, including determination of quantities transported in the diffusion tube, test of reversibility, and inversion of transport direction.
The book is a vital reference for readers interested in chemical transport reactions.

Autoren/Hrsg.

Schäfer, Harald

Inhaltsverzeichnis

1;Front Cover;1
2;Chemical Transport Reactions;4
3;Copyright Page;5
4;Table of Contents;10
5;Preface to the English Edition;6
6;Preface to the German Edition;8
7;CHAPTER 1. Introduction and Historical Review;14
8;CHAPTER 2. Experimental and Theoretical Principles ;18
8.1;2.1 Experimental Techniques;18
8.2;2.2 The Rate Determining Step in the Transport Process;26
8.3;2.3 Calculation of the Transport Effect of Heterogeneous Equilibria for a Gas Motion between Equilibrium Spaces;32
8.4;2.4 The Transport Effect and the Thermodynamic Quantities of the Transport Reaction;43
9;CHAPTER 3. The Transport of Solid Substances and Its Special Applications;48
9.1;3.1 Examples of Transportable Solid Substances;48
9.2;3.2 Separation and Purification of Substances by Means of Material Transport. Purity of Transported Material;75
9.3;3.3 Transporting Reagents as Mineralizers;88
9.4;3.4 Preparation of Single Crystals;98
9.5;3.5 Crystalline Substances with Homogeneous Regions. Mixed Crystals;105
10;CHAPTER 4. Information on the Reaction Process in the Gas Phase;112
10.1;4.1 Indications of New Gaseous Compounds;112
10.2;4.2 Systems with a Reversible Transport Direction Critical Decomposition Points;115
11;CHAPTER 5. Chemical Transport Processes as an Aid in Preparative Chemistry. Combination of Transport Reactions with Other Processes
;128
11.1;5.1 Syntheses in Temperature Gradients;129
11.2;5.2 Promotion of Reactions between Solid Substances by Transport Processes;135
12;Chapter 6. The Use of Transport Experiments in the Determination of Thermodynamic Values;146
12.1;6.1 Determination of Quantities Transported in the Diffusion Tube;146
12.2;6.2 Test of the Reversibility;148
12.3;6.3 Inversion of the Transport Direction. Critical Decomposition Point;148
13;References;156
14;Subject Index;166